nucleophilic strength. The result is a slower reaction. Polar aprotic solvents do not solvate the nucleophile very strongly‚ this results in an attack on the substrate. Therefore‚ polar aprotic solvents accelerate the rates of reaction‚ especially SN2 reactions‚ where the strength of the nucleophile determines the rate of reaction. As far as the reaction properties are concerned‚ nucleophilic attack by nitrogen on iodoethane yields N-ethylsaccharin‚ whereas nucleophilic attack by oxygen yields
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1 HIGHER SECONDARY MODEL EXAMINATION HSE II Max.marks: 60 CHEMISTRY Time: 2.45 hrs General instructions All questions are compulsory Cool-off time is 15 minutes 1] Defects modify the properties of crystals [4 marks] A] Give differences between Schottky and Frenkel defects [2.0] B] On heating zinc oxide becomes yellow in colour. Why? [1.0 ] C] Alkali metal halides on heating in presence of alkali metal produce characteristic colours.Give reason [1.0] 2] Colligative
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Provide structures for the following systematic names. Systematic name: meta-Bromopropoxybenzene Systematic name: 1-Isopropoxycyclopentene 18.2 Synthesis of Ethers The Williamson Ether Synthesis R + O an alkoxide C X R SN2 an alkyl halide methyl & 1o best; X = Cl‚ Br‚ I‚ OTos O C ether product Example: O Na + Sodium phenoxide CH3 Br O CH3 Phenyl methyl ether (anisole) + Na Br + X SP
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Victorian Certificate of Education 2012 CHEMISTRY Written examination Day Date 2012 Reading time: *.** to *.** (15 minutes) Writing time: *.** to *.** (1 hour 30 minutes) DATA BOOK Directions to students • A question and answer book is provided with this data book. Students are NOT permitted to bring mobile phones and/or any other unauthorised electronic devices into the examination room. © VICTORIAN CURRICULUM AND ASSESSMENT AUTHORITY 2012 2012 CHEM DATA BOOK 2 Table
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Lab 5 n-Butyl Bromide Preparation Introduction: The purpose of this lab is to properly extract and distill n-butyl bromide It is ideal to perform this technique with accuracy‚ which can be measured by the percent yield. Chemicals: n-Butyl Bromide- clear‚ yellow liquid that is slightly soluble in water. Molar weight of 137.02g and has zero reactivity. Sodium Bromide- white‚ crystals‚ granules. Soluble in water with no reactivity. Molar weight of 102.89g. Sulfuric Acid- colorless liquid
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t-Pentyl Chloride is a compound that is created through an SN1 nucleophilic substitution reaction in addition with Hydrogen Chloride in order to isolate the product. A variety of procedural techniques were utilized during the experiment including extraction‚ washing liquids‚ drying liquids‚ gravity filtration‚ and simple distillation. When a single solute or compound is transferred between two different solutes‚ it is known as extraction. Another technique that was utilized was washing‚ in which
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Procedure The procedure stated in Chem 2120 experiment 6 Williamson Ether Synthesis of Phenacetin laboratory manual was followed without any major changes. Data and results Compound Amount used MW (g/mol) Moles Stoichiometry/Comments acetaminophen 0.354 g 151.16 2.34 x 10-3 limiting reagent ethyl iodide 0.3mL 155.97 3.75 x 10-3 1.6 equiv ’s sodium ethoxide 2.6mL 68.05 3.3 x 10-2 catalyst‚ reaction solvent crude product obtained: phenacetin 0.32g
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CHEM 2123 and 2125 – Organic Chemistry Lab I and II GUIDELINES FOR WRITING LAB REPORTS INTRODUCTION Writing reports in organic chemistry lab may differ from the way it’s done in general chemistry. One goal of this course is to introduce you to the record keeping methods used in research labs. Such methods are designed to organize experimental data in a format similar to that required for publication in major scientific journals. Here are some important considerations that apply in research settings
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solution to create linear supramolecular assemblies containing thousands of ordered pairs‚ even without the need for purification.5 With available noncanonical nucleobases to pick from‚ and evidence of depsipeptides that could be formed in prebiotically plausible ways‚ David Fialho and Nicholas Hud designed CyAspAmide (ψD). This prebiotically plausible proto-nucleic acid monomer (Figure 1)‚ is the amide formed between a cyanuric acid-functionalized hydroxy acid called 2-OH-CyCo4 (abbreviated as
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Topic Acid-Base Theory (Unit 1) Acid-Base Theory (Unit 2) Isomerism (Unit 1) Isomerism (Unit 2) Nomenclature Reaction Mechanism (Unit 1) - Introduction to Mechanism Reaction Mechanism (Unit 2) - Nucleophilic substitution Reaction Mechanism (Unit 3) - Nucleophilic substitution Reaction Mechanism (Unit 4) - Nucleophilic substitution Reaction Mechanism (Unit 5) - Nucleophilic substitution Reaction Mechanism (Unit 6) - Nucleophilic substitution Reaction Mechanism (Unit 7) - Elimination Reaction Mechanism
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