DATE PERFORMED: JULY 20‚ 2007 SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT FOR A REACTION ABSTRACT UV-VIS spectrophotometry is one of the most widely-used methods for determining and identifying many inorganic species. During this experiment‚ this spectrophotometry was used to determine the equilibrium constant‚ Keq‚ of the Fe3+(aq)+SCN-(aq)↔ FeSCN2+(aq) reaction. By determining the amount of light absorbed‚ the concentration of the colored FeSCN2+ solution was also quantitatively
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Date Performed: January 10 & 15‚ 2013 Spectrophotometric Determination of the Equilibrium Constant of a Reaction R.J.V. Ortega and J.C.V. Gatdula Institute of Chemistry‚ College of Science University of the Philippines‚ Diliman‚ Quezon City‚ Philippines Received January 22‚ 2013 ------------------------------------------------- ------------------------------------------------- ------------------------------------------------- ABSTRACT -------------------------------------------------
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SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT OF A REACTION UNIVERSITY OF THE PHILIPPINES‚ DILIMAN QUEZON CITY‚ PHILIPPINES August 2‚ 2013 ABSTRACT The objective of this experiment is to determine the equilibrium constant‚ denoted Keq‚ for the formation of [Fe(SCN)]2+ complex which is a product of the reaction between the ions Fe3+ and SCN-. In performing this experiment‚ solutions containing FeCl3 and KSCN‚ diluted in HCl‚ were measured for their absorbance using a UV-Vis
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Spectrophotometric Determination of an Equilibrium Constant Introduction: In this experiment‚ you will study the reaction between aqueous iron (III) nitrate‚ Fe(NO3)3‚ and potassium thiocyanate‚ KSCN. They react to produce the blood-red complex [Fe(SCN)]2+. Fe3+ + SCN- ( [Fe(SCN)]2+ The equilibrium constant expression may be expressed as: K = [pic] You will prepare a series of standard solutions that contain known concentrations of [Fe(SCN)]2+ and will determine
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The Spectrophotometric Determination of an Equilibrium Constant. Abstract: The report presents determination of equilibrium constant for the formation of a complex ion FeSCN2+. This was accomplished using a colorimeter to measure absorbance of some known concentration solutions in order to generate the calibration curve. The equation of the graph was used to compute the equilibrium concentrations of the reactants and products‚ needed to calculate the equilibrium constant for
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DATE PERFORMED: JANUARY 6‚ 2011 SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION ABSTRACT The objective of the experiment was to determine the equilibrium constant of the reaction forming ferric thiocyanate through the use of Spectrophotometry. For the calibration‚ five standard solutions were prepared‚ then their respective absorbance values that were obtained through the use of the spectrophotometer‚ were plotted versus the concentration of the analyte so that a calibration
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SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION Methodology The following stock solutions were prepared: 1.0 M HCl‚ 0.1 M HCl‚ 0.1 M KSCN‚ 0.002 M KSCN (in 0.1 M HCl)‚ 0.2 M FeCl3 (in 0.1 M HCl)‚ and 0.002 M FeCl3(in 0.1 M HCl). Using the prepared stock solutions‚ the standard (Table 1) and Unknown (Table 2) solutions were prepared. Table 2. Preparation of Standard Solutions 0.10 M KSCN 0.002 M FeCl3 0.1 M HCl Blank 2.0 ml 0.0 ml 8 ml S1 2.0 ml 0.1 ml 7
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Spectrophotometric Determination of the Equilibrium Constant of a Reaction DEPARTMENT OF MATERIALS‚ METALLURGICAL AND MINING ENGINEERING‚ COLLEGE OF ENGINEERING July 26‚ 2012 ------------------------------------------------- ABSTRACT ------------------------------------------------- Before proceeding to test the next solution‚ we must first clean the cuvette‚ using similar steps earlier. First‚ we rinse with water‚ then with the solution‚ and then we fill it up and test
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CH 127 – Chem 2 Lab Determination of an Equilibrium constant Goals The purpose of this experiment is to determine the equilibrium constant for the reaction Fe3+(aq) + HSCN(aq) –>FeSCN2+(aq) + H+(aq). The equilibrium constant expression Kc for Reaction is kc=FeSCN2+[H+]Fe3++[HSCN] Procedure *Preparation of the Beer’s law plot Prepare five solutions of FeSCN2+(aq) of known concentrations between 1x10-5M and 1x10-4M by diluting various volumes of 4.62x10-4 HSCN. Calculate the Final concentration
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Determination of Equilibrium Constants Introduction Bromothymol blue is an indicator for many acid-base titrations. When adding different solutions within the indicator it is to react and change colors‚ in this experiment the different colors were blue‚ green‚ and yellow. In the following experiment‚ obtaining the absorbance levels for each one makes it possible to calculate the equilibrium constant. Materials and Methods For this specific experiment there are a few materials that are crucial
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