2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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Chapter 1 Chemical Reactions and Equations Q.1. Why should magnesium ribbon be cleaned before burning in air ? Ans: Magnesium ribbon is a very reactive metal. When stored it reacts with oxygen to form a layer of magnesium oxide on its surface. This layer of magnesium oxide being a stable compound prevents further reaction of magnesium with oxygen. The magnesium is cleaned before burning in air to remove this layer so that the metal can be exposed to air properly. Q.2. Write the balanced
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1. What is the molarity of a solution of ammonium chloride prepared by diluting 50.00 mL of a 3.79 M NH4Cl solution to 2.00 L? 2. A student takes a sample of KOH stock solution and dilutes it with 100.0 mLof water. The student determines that the diluted solution is 0.046 M KOH‚ but has forgotten to record the volume of the original stock solution sample. The concentration of the stock solution is 2.09 M. What was the volume of the original sample of stock solution? 3. A chemist wants to prepare
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Economy - overviewzz Philippine GDP grew 7.6% in 2010‚ spurred by consumer demand‚ a rebound in exports and investments‚ and election-related spending‚ before cooling to 3.7% in 2011. The economy weathered the 2008-09 global recession better than its regional peers due to minimal exposure to troubled international securities‚ lower dependence on exports‚ relatively resilient domestic consumption‚ large remittances from four- to five-million overseas Filipino workers‚ and a growing business process
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A microprocessor incorporates the functions of a computer’s central processing unit (CPU) on a single integrated circuit (IC)‚ or at most a few integrated circuits. It is a multipurpose‚ programmable device that accepts digital data as input‚ processes it according to instructions stored in its memory‚ and provides results as output. It is an example of sequential digital logic‚ as it has internal memory. Microprocessors operate on numbers and symbols represented in the binary numeral system. The
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Stoichiometry 04/09/12 Chemistry I B Ms. Norton Introduction/Pre-laboratory Assignment: 1. Write out and balance each of the following equations. A. CuSO4 + Fe Cu + FeSO4 B. 3CuSO4 + 2Fe 3Cu + Fe(SO4)3 2. If Iron (III) Sulfate were formed‚ what mass of Copper would be expected and what is the limiting reagent? C. 2.26 g Cu D. Fe 3. If Iron (II) Sulfate were formed‚ what mass of Copper would be expected and what is the limiting reagent?
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objective of this lab is to calculate the theoretical‚ actual‚ and percent yield of the product from a precipitation reaction. It is also to learn concepts of solubility and the formation of a precipitate. The Experiment and Observation: Weigh out your 1.0g of CaCl2-2H20 and put it into the 100mL beaker‚ add your 25mL of distilled water and stir to form the calcium chloride solution. Next‚ use stoichiometry to determine how much Na2CO3 and put it into a small paper cup. Then add the 25mL of distilled water
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“MOTIVATION” Filipino people are religious human being. We usually seek for guidance from our Lord in every decision we will made so in relation to that our teacher decided to have a speaker that can motivate us spiritually‚ emotionally and to enlighten us by a word of god. Fr. Joel Eslabra was the 1st invited speaker. He is a priest who is willing to share the word of God and also can give us inspiration. Fr. Joel starts his discussion with an inspirational lecture about the word of god presented
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Topic: 10-POINT AGENDAS OF PNOY REFLECTION: The Philippine Educational System is having some difficulties in resolving the different issues regarding the quality of education that we have today. Because of this‚ ‚His Excellency Benigno Simeon “Noynoy” Aquino our 14th President prioritized the upgrading of the educational system in our country. To give the Filipino people a good quality of education and for the Filipinos to be more globally competitive. One of his agenda is the
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Chapter 5 Determine the reaction order and specific reaction rate from experimental data obtained from batch reactors. Describe how to use numerical difference formulas to analyze experimental data to determine the rate law. 5.1 Differential and integral method for batch data Describe how the methods of half lives and of initial rate are used to analyze rate data. 1 3/28/2014 When a reaction is irreversible‚ the reaction order‚ α and the specific rate
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