CM5121 Graduate Organic Chemistry General Administration Matters Dr. Zhang Sheng Office no: S7-03-12 Email: chmzs@nus.edu.sg CM5121 Assessments CA (quiz‚ project) 50% Final Exam (Closed Book) 50% CA: choose 2 out of 3 Quiz 1 (Week 7‚ closed book) 25% Quiz 2 (Week 11‚ closed book) 25% Project Presentation 25% (Week 11-13) 2 Syllabus Broadly divided into 2 parts: 1) Pericyclic Reactions i) Electrocyclic ii) Cycloaddition and cycloreversion iii) Sigmatropic 2) Rearrangements
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Organic chemistry Organic chemistry is one of the ‘branches’ of chemistry and is seen as distinct from other branches‚ such as inorganic and physical chemistry. It can be described as the chemistry living processes (often referred to as biochemistry) but extends beyond that. It focuses almost entirely on the chemistry of covalently bonded carbon molecules and as well as life processes‚ it includes the chemistry of other types of compounds‚ including plastics‚ petrochemicals‚ drugs and paint
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Organic Lab I No. 5-6 Separation of a Carboxylic Acid‚ a Phenol‚ and a Neutral Substance (Two-week lab) Reading Assignment 1) Chapter 7 • Introduction: P. 135- first paragraph • Theory and Techniques (p142-145) o Properties of Extraction Solvents o Mixing and Separating the Layers o Drying Agents o Part 1: The Technique of Neutral Liquid/Liquid Extraction The description is for dichloromethane-aqueous
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Organic Lab Part 2 Experiment 7: Diethyl n- Butylmalonate Lab Partner: Reference: Williamson K.L.‚ & Masters‚ K.M. (2011).”Diethyl n- Butylmalonate”. Macroscale and Microscale Organic Experiments ( 6th edition pp. 531-534)
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educator Friedrich Froebel designed‚ the organic unity of a Japanese building Wright saw at the Columbian Exposition in Chicago in 1893‚ and a Jeffersonian belief in individualism and populism. Always a believer in architecture as "natural" and "organic‚" Wright saw it as serving free individuals who have the right to move within a "free" space‚ envisioned as a nonsymmetrical design interacting spatially with its natural surroundings. He sought to develop an organic unity of planning‚ structure‚ materials
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CLASSIFICATION TESTS A. Acids There are relatively few suitable tests for carboxylic acids. Classification is based mostly upon solubility tests. If the compound is water soluble‚ test the aqueous solution of your compound with pH paper (also check the pH of the original water). If the compound is water-insoluble and it dissolves in 5% (1.5M) sodium hydroxide and 5% NaHCO3 solutions as performed in your solubility tests‚ it can be classified as a carboxylic acid. Establish an equivalence value
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(in the second centrifuge tube). Now wash (microscale) the combined extracts with saturated NaCl solution (5mL)‚ then with 10% aqueous potassium carbonate (5mL)‚ then with saturated NaCl solution (5 mL) again. Dry the organic layer with anhydrous sodium sulfate. Decant the organic layer into a small beaker and concentrate to roughly 0.2 mL by evaporation in the hood (do not apply heat!). If the sample goes to dryness‚ re-dissolve in hexane (0.2 mL). *Set aside a small amount of your crude
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Chapter 17—Alcohols and Phenols SHORT ANSWER Drawing Instructions: Draw structures corresponding to each of the given names. 1. Draw: cis-4-tert-butylcyclohexanol ANS: 2. Draw: 3-methyl-2-buten-1-ol ANS: 3. Draw: 2-phenyl-2-propanol ANS: 4. Draw: glycerol ANS: 5. Draw: 2‚ 4‚ 6-trinitrophenol ANS: IUPAC Naming Instructions: Provide proper IUPAC names. 6. Name: ANS: (E)-2-ethylbut-2-en-1-ol 7. Name: HOCH2CH2OH ANS:
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You Decide – Smackey Dog Foods Inc Smackey Dog Foods‚ Inc. is a familiar story in terms of small business start-ups. They started in a family kitchen‚ experienced explosive growth‚ and have had some troubles handling the accounting and business side of the business. My firm‚ Keller CPA’s‚ does not have specific experience with auditing a dog food manufacturer‚ but we certainly have a good bit of experience with similar small business accounting and auditing issues. The first thing to address
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Partitioning of organic acid food preservatives between oil and water Olaya Iturbe Navalpotro Student of Food National Institute -DTU Technical University of Denmark Index 1. Introduction …………………………………………………………..pg. 2-4 2. Theoretical background……………………………………………….pg. 5-18 2.1. Preservatives (Sorbic acid and Benzoic acid) 2.2. Solubility and partitioning of food preservatives in food system 2.3. Measurements of the preservatives partitioning in oil-water system 2.4. Influences of
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