Organometallic preparation and addition to carbonyls‚ Wittig reagent preparation and Wittig rxn‚ Wolff‚ H-based nucleophile carbonyl reduction‚ imine formation‚ reductive amination (rxn only)‚ ketal/acetal formation‚ dithiane chemistry (rxn only)‚ alpha-bromination of ketones‚ -COOH properties (the trends on HW4)‚ Fischer‚ acidic/basic hydrolysis of esters/amides/nitriles‚ CH2N2‚ acid chloride formation (rxn only)‚ acid chloride rxns with esters and amides. 2 Rxn of carboxyllic acid derivatives
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CHEMISTRY 101.1 Intermediate Chemistry Laboratory I Institute of Chemistry University of the Philippines‚ Diliman I. Synthesis of Salicylic Acid Purpose: Part I of the experiment illustrates the base hydrolysis of an ester‚ methyl salicylate‚ to form salicylic acid through nucleophilic acyl substitution. Procedure: Dissolve 12 g NaOH in 70 mL water in a 150 mL round bottom flask. Add 5.0 mL methyl salicylate and reflux the reaction mixture at its boiling point for 15 minutes using a stirrer
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Key Questions Lesson 1 1. One argument against continuing research on the atom is that the cost continues to increase at an alarming rate‚ and the benefits seem to be declining. Whereas quantum chemistry experiments as early as 80 years ago were very cheap and yielded considerable practical results‚ now very few if any practical results are emerging‚ but the costs of experiments continues to increase. On the other hand a common argument for the continued
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CHEM3412 Synthesis of a Porphyrin Porphyrins are hetereonuclear‚ macrocyclic compounds that play an important role in living organisms. Examples include the non-protein heme portion of hemoglobin in animals whereby the lone pairs on nitrogen can bind to the oxygen-carrying iron. In plants‚ chlorophyll uses the vast conjugation to allow absorption of light for photosynthesis. The characteristic colors of porphyrins is also due to the conjugation. An examination of the porphyrin structure
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|Faculty of Engineering & Science | |Unit Code |: |UEMK1013 | |Course |: |Chemical Engineering | |Unit Title |: |Chemistry for Engineering | |Year/ Semester |: |Year 1/ Trimester 1 | |Lecturer |: |Dr. Loh Han Chern | |Session |: |201101
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Jennie K. Daniels Organic Chemistry 2121 11 February 2014 Synthesis of Aspirin Salicylic acid derivatives‚ or salicin‚ are found in the bark of the willow tree. In the 5th century B.C.‚ Hippocrates ground the bark into a powder‚ and later‚ the Natives Americans chewed on the bark to alleviate fever and pain1. In the 19th century‚ a German chemist by the name of Felix Hoffman wanted to find a medication that would ease
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Synthesis of Acetanilide By: Rick Whitely April 9‚ 2013 Organic Chemistry Lab 1; Professor J. Hutchison Recrystallization is a common method of purifying organic substances through the differences in solubility at different temperature. In this experiment‚ acetanilide was produced by acetylation of aniline with acetic anhydride. The crude acetanilide was dissolved in a solvent in a heated water bath. The solution was cooled slowly in an ice bath as crystals form out. As the compound crystallizes
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CHEM 301 LECTURE Unit 1 0 . COORDINATION CHEMISTRY Factors t hat affect solubility: Common ion: decrease in solubility Complex ion: increase in solubility How does complex ion formation increase solubility? Consider the complex ion formation between silver and ammonia: + Ag + 2NH3 A g(NH3 )2 + Kf = 1 .5 x 10 7 where Kf i s the formation constant (always >1 ‚ formation of the complex is highly favorable) Complex ion formation increases the solubility of sol ids in water
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experimental techniques which can be used to tell us where the atoms are located in a molecule. Using advanced techniques‚ very complicated structures for proteins‚ enzymes‚ DNA‚ and RNA have been determined. Molecular geometry is associated with the chemistry of vision‚ smell and odors‚ taste‚ drug reactions and enzyme controlled reactions to name a few.
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ical Chemistry 1.which of the following pairs of compound will react? iC3H6+Br2 iiC3H6+Cl2 in sunlight iiiC3H6+H2O in the presence of sulphuric acid ivC3H6+H2O in the presence of concentrated sulphuric acid a.i b.i‚iii c.i‚ii‚iii d.all 2.liqiud y reacts with magnesium metal to produce a gas that burns with a pop sound when a flaming wooden splint is placed near it.liqiud y is most likely a compound that has the formula a.c2h5oh b.hcooh c.h3cooch3 d.c6h14 3.a compound p has the
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