nitrogens on this station. Both of these methods rely on the repulsive electrostatic interactions between the positively charged axial component and the post-switching cationic nature of the benzidine station (Figure 5.4). Deuterated trifluoroacetic acid (d-TFA) was added in the solution which resulted in the protonation of the benzidine residue and shuttling of macrocycle in to the biphenol station of the Rotaxane. This was supported by NOESY 1H NMR that showed a shift in the peaks in retrospect to
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The book “Purity of Heart” is a composition of letters written by the founder William Booth. Originally‚ these letter were shared in weekly Salvation Army gatherings to help Salvationists continue in Holiness‚ then later they were put in book form. Holiness is viewed as synonymous to a “pure heart; this is define in chapter eight‚ by William booth. The book is divided in ten chapters that are interrelated and build upon each other. It begins by defining purity of the heart in general terms. Next
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Chapter 4: Nucleic Acids and the RNA World 1. 4.1 – What is a Nucleic Acid? * Nucleic acids are made up of monomers called nucleotides * Three components of a nucleotide: 1. Phosphate group—attached to the 5’ carbon 2. Sugar – carbonyl group and several hydroxyl groups 3. Nitrogenous base * The prime (‘) symbols indicate the carbon being is part of the sugar—not attached to the nitrogenous base. * Four different nucleotides‚ each of which contains a different nitrogenous
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PRE - DETERMINATION 1. One day‚ you feel as if you are going to meet someone. Fortunately‚ you meet that person on the same day. But my question is‚ “How did you feel that you will meet that person that day?” 2. Few incidents in our life happen accidentally‚ but you will feel as if the same incident has happened already‚ but you won’t be able to remember when exactly it happened! My question is‚ “Was that feeling real?” A solution to all such questions is this “THEORY OF PRE-DETERMINATION”. This
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Pickling and Passivating Stainless Steel Materials and Applications Series‚ Volume 4 Euro Inox Euro Inox is the European market development association for stainless steel. The members of the Euro Inox include: • European stainless steel producers • National stainless steel development associations • Development associations of the alloying element industries. The prime objectives of Euro Inox are to create awareness of the unique properties of stainless steels and to further their
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Acid-Base Extraction: Separation of an Organic Acid‚ Base and a Neural Compound Introduction/Background Acid base extraction is a widely used commercial method in separating acids‚ bases and neutral compounds. This is concept is based on several physical properties of the compounds‚ such as boiling point‚ melting points and solubility. The different solubility properties of the protonated and non-protonated forms of these compounds depend on the functional groups present‚ such
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Worksheet - Acids‚ Bases and Salts 1. I am pure water. When heated my pH (increases‚ decreases)‚ because more of my water molecules dissociate. 2. I am a 0.020 M solution of weak acid‚ HA. If I only dissociate to the extent of 1.50%‚ what is the value of my Ka? 3. I am a 0.20 M solution of hydrocyanic acid‚ HCN‚ with a Ka of 4.93 x 10¯ 10 . What is my pH? 4. I am a buffer made from 0.10 M acetic acid and 0.15 M sodium acetate. If the Ka for acetic acid is 1.77 x 10¯ 5 ‚ what is my pH? 5. I am
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Acid Rain Acid rain occurs when Sulphur Dioxide (SO2) is released into the atmosphere by electricity generation‚ motor vehicles‚ factories and by wildfires and volcanoes. Once released‚ the sulphur dioxide reacts with water to produce sulphuric acid. This has a pH of approximately 2-3 pH. This has a dramatic effect on water dwelling wildlife. Most water dwelling creatures can’t withstand water more acidic than pH 5. This causes the mass loss of life of animals such as trout‚ perch‚ frogs and mayflies
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10/19/2011 Akruti Patel Lab Report #4: Determination of a chemical formula: the empirical formula of Magnesium Oxide 1. Purpose: Determine the empirical formula of magnesium oxide from the percent composition (this can found using the Analytical Method and the Synthesis Method). 2. Introduction: In the late eighteenth century‚ combustion has been studied extensively. In fact‚ according to Steven and Susan Zumdahl‚ Antoine Lavoisier‚ a French Chemist‚ performed thousands of combustion experiments
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The Purity and Purification of Solids Melting Point Lab Introduction: The point of this lab was to determine the eutectic point for the naphthalene biphenyl mixture‚ as well as determining the melting point of an unknown substance by comparing it with two known samples. Melting point is a temperature in which a substance changes from solid state to liquid state. Melting points are used to determine whether the given substance is pure or not. Substances that melt sharply‚ less than 1-2°C indicates
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