Compound 50‚ like its known analogue 3‚ involves an α‚β-unsaturated ketone‚ an acid-sensitive reactant‚ which prevents its direct synthesis in presence of protic solvents by refluxing. Despite of this characteristic‚ 50 was formed smoothly in 5 minutes by grinding chemistry‚ solely as E-isomer‚ without any evidence of decomposition after 1H and 13C MNR analysis. This synthetic approach provides easy access to such α‚β-unsaturated N-acylhydrazones‚ which are building blocks in the synthesis of nitrogen-containing
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Draft 3 Engaging and Retaining older workers in Rural Community Aged Care The scope of this paper is to look at effective ways to engage and retain older workers to deliver quality community Aged care services in rural Australia. The ageing population has resulted in a necessity to recruit older workers to fill positions in all industries including the aged care sector. "We are in the midst of the most significant demographic shift in modern human history where populations across the globe are
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50 First Dates Henry Roth is a marine-life veterinarian at Sea Life Park on the island of Hawaii who has a reputation of being a ladies man and targets female tourists and he has no interest in committing to a serious relationship with these ladies. He constantly gives these women excuses as to why he can’t give them his number. He owns an old boat which he plans to use to fulfil his dream. His friend Ula who happens to be his workmate and his closest friend is a marijuana-smoking Islander and Henry’s
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Unfair Dismissal of Agency Workers or Unfair Legislation in the UK for Businesses using Agency Workers? Abstract The contribution encapsulates a legal discussion on the controversial figure of the agency workers‚ from the judicial debate blossomed during the last decade in the British courts‚ as regards their legal characterization‚ until the most recent developments‚ particularly the legislative framework passed in Britain‚ the Agency Workers Regulations. On such footings‚ the investigation focuses
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By the end of the nineteenth century‚ the United Sates had become the ideal destination for immigrant workers. Immigrants from various countries all over the world flocked to America in hopes of finding work in the growing industrial sector. Many immigrants that migrated to America had intentions of either establishing a life for themselves in the states or sending money back home to support their families in their home countries (Goldberg‚ ed. 7‚ The American Journey‚ 523). The type of work that
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TV in the 50s and 60s Throughout the 1950s television fought to become the top form of mass communication‚ and became a cultural force in good and bad ways by the 60s. Before the end of the 1960s over three national networks began were broadcasting programs that were alternately earth shaking‚ sublime and ridiculous. During 1940s‚ the three major networks consisted of: NBC‚ CBS and ABC were "networks" by name only. All programming show originated‚ live‚ in New York. The only possible way to dispense
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1960’s originated in the 50’s‚ including new attitudes toward sex and the family and a new interest in ethnicity and diversity. Jewish and black writers‚ even a few openly gay writers‚ cut a path for the multicultural writers of the 80’s and 90’s. The margins of the culture were beginning to erode the conservative center. Elvis was influenced by black rhythm and blues‚ while writers like Norman Mailer and Jack Kerouac idealized black culture. Counterculture writers of the 50’s were fascinated by jazz
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General The 50’s was the decade that gave us the still well known and well loved music genre of Rock’n’Roll. Other than Rock’n’Roll country music‚ traditional pop‚ and rhythm and blues were the main genres of the 50’s. Rock’n’Roll Bill Haley & His Comets‚ a group that was founded in 1952‚ were some of the first to play this specific genre In 1954 the Bill Haley’s “Rock Around the Clock” became the first song ever used for a movie’s soundtrack. Is believed to be a mix of rhythm‚ blues‚ and country
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1950’s have been put into stereotypical boxes created by other people‚ objectified and made into a mean for entertainment for certain parts of the public‚ all within the format of the magazine. I will look at early magazines where the housewife of the 50’s are represented‚ magazines where women are nude and made into sex symbols‚ where women are not being considered at all but there to sell an item to the public. How have all of these representations and different portrayals of the female sex within
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As an educator its essential to get a good understanding of each child’s family life‚ traditions‚ culture as much as you would their sleep routine‚ food‚ interest etc. Having an understanding of a child’s world at home and at childcare is the best way to understand their behaviour‚ expectations and personality. Without knowing such a big part of their life it would be unrealistic to try and plan for them in the class‚ as you may not have taken their needs or wants into account. Understanding the
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