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Controlling n-Heptane HCCI
Combustion With Partial
Reforming: Experimental Results and Modeling Analysis
Vahid Hosseini
W. Stuart Neill
Institute for Chemical Process and
Environmental Technology,
National Research Council,
Ottawa, ON, K1A 0R6, Canada

M. David Checkel
University of Alberta,
Edmonton, AB, T6G 2G8, Canada

1

One potential method for controlling the combustion phasing of a homogeneous charge compression ignition (HCCI) engine is to vary the fuel chemistry using two fuels with different auto-ignition characteristics. Although a dual-fuel engine concept is technically feasible with current engine management and fuel delivery system technologies, this is not generally seen as a practical solution due to the necessity of supplying and storing two fuels. Onboard partial reforming of a hydrocarbon fuel is seen to be a more attractive way of realizing a dual-fuel concept, while relying on only one fuel supply infrastructure. Reformer gas (RG) is a mixture of light gases dominated by hydrogen and carbon monoxide that can be produced from any hydrocarbon fuel using an onboard fuel processor. RG has a high resistance to auto-ignition and wide flammability limits. The ratio of H2 to CO produced depends on the reforming method and conditions, as well as the hydrocarbon fuel. In this study, a cooperative fuel research engine was operated in
HCCI mode at elevated intake air temperatures and pressures. n-heptane was used as the hydrocarbon blending component because of its high cetane number and well-known fuel chemistry. RG was used as the low cetane blending component to retard the combustion phasing. Other influential parameters, such as air/fuel ratio, EGR, and intake temperature, were maintained constant. The experimental results show that increasing the RG fraction retards the combustion phasing to a more optimized value causing indicated power and fuel conversion efficiency to increase. RG reduced the first stage of heat



References: ͓1͔ Upatniek, A., Mueller, C. J., and Martin, G. C., 2005, “The Influence of Charge-Gas Dilution and Temperature on DI Diesel Combustion Processes Using a Short-Ignition-Delay, Oxygenated Fuel,” SAE Paper No. 2005-012088. ͓2͔ Sjöberg, M., and Dec, J. E., 2003, “Combined Effects of Fuel-Type and Engine Speed on Intake Temperature Requirements and Completeness of Bulk-Gas Reactions for HCCI Combustion,” SAE Paper No. 2003-01-3173. ͓3͔ Christensen, M., Hultqvist, A., and Johansson, B., 1999, “Demonstrating the Multi-Fuel Capability of a Homogeneous Charge Compression Ignition Engine With Variable Compression Ratio,” SAE Paper, 1999-01-3679. ͓4͔ Stanglmaier, R. H., Ryan, T. W., and Souder, J. S., 2001, “HCCI Operation of a Dual-Fuel Natural Gas Engine for Improved Fuel Efficiency and Ultra-Low NOx Emissions at Low-to-Moderate Engine Loads,” SAE Paper No. 2001-011897. ͓5͔ Zheng, Z., Yao, M., Chen, Z., and Zhang, B., 2004, “Experimental Study on HCCI Combustion of Dimethyl Ether ͑DME͒/Methanol Dual Fuel,” SAE Paper No ͓6͔ Jamal, Y., and Wyszynski, M. L., 1994, “On-Board Generation of HydrogenRich Gaseous Fuels—A Review,” Int. J. Hydrogen Energy, 19͑7͒, pp. 557– 572. ͓7͔ Dicks, A. L., 1996, “Hydrogen Generation From Natural Gas for the Fuel Cell Systems of Tomorrow,” J ͓8͔ Shudo, T., 2006, “An HCCI Combustion Engine System Using On-Board Reformed Gases of Methanol With Waste Heat Recovery: Ignition Control by Hydrogen,” Int ͓9͔ Tsolakis, A., and Megaritis, A., 2005, “Partially Premixed Charge Compression Ignition Engine With On-Board H2 Production by Exhaust Gas Fuel Reforming of Diesel and Biodiesel,” Int. J. Hydrogen Energy, 30, pp. 731–745. ͓10͔ Eng, J. A., Leppard, W. R., and Sloane, T. M., 2002, “The Effect of POx on the Autoignition Chemistry of n-Heptane and Iso-Octane in an HCCI Engine,” SAE Paper No. 2002-01-2861. ͓11͔ Hosseini, V., and Checkel, M. D., 2006, “Using Reformer Gas to Enhance HCCI Combustion of CNG in a CFR Engine,” SAE Paper No ͓12͔ Hosseini, V., and Checkel, M. D., 2007, “Effect of Reformer Gas on HCCI Combustion—Part I: High Octane Fuels,” SAE Paper No ͓13͔ Hosseini, V., and Checkel, M. D., 2007, “Effect of Reformer Gas on HCCI Combustion—Part II: Low Octane Fuels,” SAE Paper No ͓14͔ Hosseini, V., and Checkel, M. D., 2005, “Alternative Mode Combustion Study: HCCI Fueled With Heptane and Spark Ignition Fueled With Reformer Gas,” ͓15͔ Mueller, C. J., 2005, “The Quantification of Mixture Stoichiometry When Fuel Molecules Contain Oxidizer Elements or Oxidizer Molecules Contain Fuel Elements,” SAE Paper No. 2005-01-3705. ͓16͔ Heywood, J. B., 1988, Internal Combustion Engine Fundamentals, McGrawHill, New York. ͓17͔ Chang, J., Güralp, O., Filipi, Z., Assanis, D., Kuo, T.-W., Najt, P., and Rask, R., 2004, “New Heat Transfer Correlation for an HCCI Engine Derived From Measurements of Instantaneous Surface Heat Flux,” SAE Paper No. 2004-012996. ͓18͔ Hosseini, V., and Checkel, M. D., 2008, “Reformer Gas Composition Effect on HCCI Combustion of N-Heptane, Iso-Octane, and Natural Gas,” SAE Paper No. 2008-01-0049. ͓19͔ Hosseini, V., 2008, “Reformer Gas Application in HCCI Combustion Engine,” Ph.D ͓20͔ Kongsereeparp, P., Kashani, B., and Checkel, M. D., 2005, “A Stand-Alone Multi-Zone Model for Combustion in HCCI Engines,” ASME Internal Combustion Engine Fall Technical Conference, Ottawa, Canada, Paper No. Reformed Fuel Blending in a Natural Gas- and N-Heptane-HCCI Engine Using a Multi-Zone Model,” SAE Paper No. 2007-01-0205. ͓22͔ Kongsereeparp, P., and Checkel, M. D., 2007, “Novel Method of Setting Initial Conditions for Multi-Zone HCCI Combustion Modeling,” SAE Paper No. ͓23͔ Kongsereeparp, P., and Checkel, M. D., 2007, “Investigating the Effects of Reformed Fuel Blending in a Methane- or N-Heptane-HCCI Engine Using a Multi-Zone Model,” SAE Paper No. 2007-01-0205. ͓24͔ Golovichev, V., 2007, http://www.tfd.chalmers.se/~valeri/MECH.html. ͓25͔ Hosseini, V., Neill, W. S., and Checkel, M. D., 2008, “Controlling N-Heptane HCCI Combustion With Partial Reforming: Experimental Results and Modeling Analysis,” ASME Internal Combustion Engine Spring Technical Conference, Chicago, IL, Paper No ͓26͔ Subramanian, G., Da Cruz, A. P., Bounaceur, R., and Vervisch, L., 2007, “Chemical Impact of CO and H2 Addition on the Auto-Ignition Delay of ͓27͔ Shudo, T., and Yamada, H., 2007, “Hydrogen as an Ignition-Controlling Agent for HCCI Combustion Engine by Suppressing the Low-Temperature Oxidation,” Int ͓28͔ Peng, Z., Zhao, H., and Ladommatos, N., 2003, “Effects of Air/Fuel Ratios and EGR Rates on HCCI Combustion of N-Heptane, a Diesel Type Fuel,” SAE Paper No. 2003-01-0747. ͓29͔ Docter, A., and Lamm, A., 1999, “Gasoline Fuel Cell Systems,” J. Power Sources, 84, pp ͓30͔ Dean, J. A., 1999, Lange’s Handbook of Chemistry, 15th ed., McGraw-Hill, New York. ͓31͔ Shudo, T., and Takahashi, T., 2004, “Influence of Reformed Gas Composition on HCCI Combustion of Onboard Methanol-Reformed Gases,” SAE Paper No. 2004-01-1908.

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