The probe
The pH probe measures pH as the activity of hydrogen ions surrounding a thin-walled glass bulb at its tip. The probe produces a small voltage (about 0.06 volt per pH unit) that is measured and displayed as pH units by the meter. For more information about pH probes, see glass electrode.
Building a pH meter
Because the circuitry of a basic pH meter is quite simple, it is possible to build a serviceable pH meter or pH controller with parts available at a neighborhood electronics retailer. (pH probes, however, are not so easily acquired and must usually be ordered from a scientific instrument supplier.) For a walkthrough of how to build the simplest possible pH meteror a detailed description of how to build a pH meter/pH controller, see The pH Pages. The application note for the LM6001chip at the National Semiconductor web site also has a very simple demonstration circuit. Although the application note is for a specialty IC, serviceable pH meters can be built from any operational amplifier with a high input impedance, such as the common and inexpensive National Semiconductor TL082 or its equivalent.
Calibration and use
For very precise work the pH meter should be calibrated before and after each measurement. For normal use calibration should be performed at the beginning of each day. The reason for this is that the glass electrode does not give a reproducible e.m.f. over longer periods of time.
Calibration should be performed with at least two standard buffer solutions that span the range of pH values to be measured. For general purposes buffers at pH 4 and pH 10 are acceptable. The pH meter has one control (calibrate)