Preview

Potentiometric Titration of Iron with Mohr's Salt

Better Essays
Open Document
Open Document
767 Words
Grammar
Grammar
Plagiarism
Plagiarism
Writing
Writing
Score
Score
Potentiometric Titration of Iron with Mohr's Salt
Potentiometric Titrations

Accuracy

The accuracy of a potentiometric analysis is limited by the measurement error for the cell's potential. Several factors contribute to this measurement error, including the contribution to the potential from interfering ions, the finite current drawn through the cell while measuring the potential, differences in the analyte's activity coefficient in the sample and standard solutions, and liquid junction potentials. Errors in accuracy due to interfering ions often can be eliminated by including a separation step before the potentiometric analysis.

Precision

The precision of a potentiometric measurement is limited by variations in temperature and the sensitivity of the potentiometer.

Time, cost & equipment

In comparison with competing methods, potentiometry provides a rapid, relatively low-cost means for analyzing samples. Commercial instruments for measuring pH or potential are available in a variety of price ranges and include portable models for use in the field.

Classical Titrations

Accuracy

An important limitation when using a visual indicator is the need to observe the change in color signaling the end point. This may be difficult when the solution is already colored. When working with macro–major and macro–minor samples, acid–base titrations can be accomplished with relative errors of 0.1–0.2%. The principal limitation to accuracy is the difference between the end point and the equivalence point.

Precision

The relative precision depends primarily on the precision with which the end point volume can be measured and the precision of the end point signal. The relative precision can be improved by using the largest volume buret that is feasible and ensuring that most of its capacity is used to reach the end point. The precision of the end point signal depends on the method used to locate the end point. With a visual indicator, the precision of the end point signal is usually between ±0.03 mL and

You May Also Find These Documents Helpful

  • Satisfactory Essays

    Chem Lab

    • 333 Words
    • 2 Pages

    Precision is how accurately measured or correct something is. It is important to be precise because it gives credibility to test results…

    • 333 Words
    • 2 Pages
    Satisfactory Essays
  • Good Essays

    6.03 Calorimetry Lab

    • 992 Words
    • 4 Pages

    Using the buret to read the volume of water is a source of random error because it is marked to the nearest 0.1mL. Therefore, our data could be above or below the actual volume of water in the buret because we took our reading to the nearest 0.01mL, which increases our uncertainty level. Along with taking our volume readings to the nearest 0.01mL, a random error also arose when we took the reading of the temperature of the water. The thermometer only read to the nearest tens places, therefore our readings went to only the tenths place which could have been measured inaccurately giving rise to more uncertainty and random error within the lab. We were able to limit our uncertainty level when taking the masses of the beaker with and without water, by using the analytical balances which read to the nearest ±0.0001g.…

    • 992 Words
    • 4 Pages
    Good Essays
  • Better Essays

    Titration is a method, which is meant to find the concentration of either an acid or a base by adding a measured amount of it to a known volume and concentration of an acid or base1. Titration starts with a beaker or Erlenmeyer flask containing a very precise volume of the known concentration solution and a small amount of indicator, which is put underneath a burette containing the solution with unknown concentration1. Small drops of the titrant are then added to the known solution and indicator until the indicator changes which means the endpoint has been reached. Single drops of the titrant can sometimes make a permanent or temporary change in the indicator2.…

    • 2337 Words
    • 10 Pages
    Better Essays
  • Good Essays

    LAB 2

    • 1482 Words
    • 7 Pages

    The 10mL graduated cylinder is capable of the greatest precision. Using this cylinder allows the experimenter to estimate to the hundredths place. Accuracy refers to how closely a…

    • 1482 Words
    • 7 Pages
    Good Essays
  • Powerful Essays

    min . The calibration curve was linear over the range 0.1-5.0μg/ml. The method was also suitable for the…

    • 3534 Words
    • 26 Pages
    Powerful Essays
  • Powerful Essays

    In the titration, I used these available instruments to ensure my results would be as accurate as possible.…

    • 1424 Words
    • 5 Pages
    Powerful Essays
  • Good Essays

    Look at the calibration marks on your ruler to determine the degree of uncertainty and number of significant figures that can be made when measuring with a ruler.…

    • 2629 Words
    • 11 Pages
    Good Essays
  • Good Essays

    Balance Lab

    • 1933 Words
    • 8 Pages

    Use centigram balance #1. Clean the platform with a lint free cloth and check that all weights on the beams are in the zero position. Check to make sure that the centigram beam indicator aligns with the arrow on the stand. If zero, place object in the center of the platform and move beam weights until the beam indicator realigns with the arrow. Record the weight measurement.…

    • 1933 Words
    • 8 Pages
    Good Essays
  • Good Essays

    Microscale Lab

    • 709 Words
    • 3 Pages

    (e) Reliability of microscale experiments in general – use % errors in the automated pipets and your calibrated pipets for error…

    • 709 Words
    • 3 Pages
    Good Essays
  • Better Essays

    Lab Three

    • 1684 Words
    • 7 Pages

    As important as a measurement is there a knowledge of the uncertainty associated with the. (For instance, when using instrument such as scales and thermometers, there is always a margin of error.) In our lab work it is important to keep such uncertainties in mind and use conversions to measure such measurement against other units of measurement measurements to insure the most accurate data during laboratory experiments. The utilization…

    • 1684 Words
    • 7 Pages
    Better Essays
  • Good Essays

    Unknown Acid Titration

    • 1249 Words
    • 5 Pages

    The concentration of one solution was determined by its reaction with a standard solution. The molar mass of unknown acids were also calculated. While learning to titrate, I learned several other skills in the process. I learned how to prepare a standard solution of sodium hydroxide, how to standardize a sodium hydroxide solution by using potassium hydrogen phthalate (KHP), how to find the molar masses of unknown organic acids when given whether the acid is monoprotic, diprotic, or triprotic, and how to calculate the molarity of a soft drink. At the same time, other skills were practiced. Skills such as calculating molarity, molar mass and percent error were exercised.…

    • 1249 Words
    • 5 Pages
    Good Essays
  • Good Essays

    Titration can be traced to the origins of volumetric analysis, which began in the late eighteenth century. Study of analytical chemistry began in France and the first burette was made by Francois Antoine Henri Descroizilles. The field began to spread to neighboring countries and eventually to the whole world. Titration can be defined as the gradual addition of one solution to another until the chemical amount of one reactant being added matches stoichiometrically the amount of another reactant in the solution initially present. Learning the right technique of Titration is essential because of its wide applications in all areas of science, it is used in laboratory medicine to determine unknown concentrations of chemicals of interest in blood and urine. Pharmacists also use titration in the development of new pharmaceuticals. Titration may also be used to determine the amount of a certain chemical in food. Often, titration is used to determine fat content, water content, and concentrations of vitamins. It is also used to tell if cheeses and wines have aged enough for distribution to supermarkets and shops. Scientists of different disciplines use titrations for a variety of different reason. [1]…

    • 735 Words
    • 3 Pages
    Good Essays
  • Better Essays

    Ph Level Lab Report

    • 638 Words
    • 3 Pages

    The pH level was recorded and the electrode rinsed with distilled water and patted dry with a KimWipe. Next, 22 mL of milk of magnesia were measured and placed in a 50mL beaker. The electrode was placed in milk of magnesia and the pH level was recorded and the electrode rinsed with distilled water and patted dry with a KimWipe. Finally, 22 mL of distilled water was placed in a beaker. The electrode was placed in the beaker and the pH level was recorded and the electrode rinsed with distilled water and patted dry with a KimWipe. This method was repeated twice more for a total of 3 trials. Water was the control variable, while the dependent variable was measuring the pH levels of orange juice and milk of magnesia. And the independent variable was by using different…

    • 638 Words
    • 3 Pages
    Better Essays
  • Good Essays

    Titration of Acetic Acid

    • 1591 Words
    • 7 Pages

    Conducting a Titration is the Process of Applying a Balanced Chemical Equation to Determine the Volume of a Solution with an Unknown Molarity or Concentration that is Need to React with a Pre-Determined Amount of a Second Solution of a Known Molarity and Concentration. In order to Achieve a Proper Titration, however, a great deal of measuring, preparation, and precision was required from me; beginning with arranging the equipment so that the Stop Cock Tip of the Test Tube located in the Elevated Clamp Handle is located approximately one to two centimeters above the beaker where the Color Change in the Titration Indicator, in this case Phenolphthalein, is to be observed. I then proceeded to Pour and Measure 9.9 mL of 0.5 Sodium Hydroxide Solution, taking care to allow a few drops of the Sodium Hydroxide Solution to drip into the Beaker, in order to Ensure a More Accurate Reading of the Volume of Solution Used Once the Experiment was Preformed. Once the Beaker was rinsed with Distilled water and the Initial Volume of Sodium Hydroxide was Recorded, the Experiment proceeded by Pouring and Measuring 5 mL of President’s Choice Vinegar into the Beaker and Subsequently adding two drops of the Titration Indicator, Phenolphthalein to the Beaker. Now Came the Reaction Portion of the Experiment, where I took care to Open the Stopcock with Such a Steady Flow that it would Add Only One Drop of Sodium Hydroxide ever Two to Three Seconds, while Simultaneously Counting and Keeping Track of How Many Drops of…

    • 1591 Words
    • 7 Pages
    Good Essays
  • Good Essays

    Chem Pre-Lab

    • 635 Words
    • 3 Pages

    In Figure 2, the lower meniscus lies below the 3 mL line and 4 minor gradations that signify 0.1 values. Estimating the uncertain digit to be 0.04 mL, the reading we record for this particular buret is 3.44 mL.…

    • 635 Words
    • 3 Pages
    Good Essays

Related Topics