Polymers a large molecules made up of a chain of smaller molecules, known as monomers. The monomers that a polymer is made up of decide its structure and therefore it's function. These monomers are linked and coiled in a very specific manor giving the polymer a specific tertiary structure (an extensively coiled and linked polymer chain caused as a result of the formation of more bonds forming). This tertiary structure is crucial to the function of a polymer as it denotes the necessary shape of the complementary molecule. This is easier explained through an example.…
Polymers are large macromolecules composed of many small repeating subunits (monomers) connected via covalent bonds. Both natural and synthetic polymers are created via polymerization of these small molecules (Chemistry 144 Writing Assignment information sheet). The chosen polymer, polytetrafluoroethylene (PTFE) in the form of Teflon®, is a synthetic fluoropolymer of tetrafluoroethylene (Wikipedia, 2015), and is one of the most well-known brand names for PTFE based formulas, owned by DuPont Co.…
Polyvinyl Chloride, otherwise known as PVC is a hard plastic pipe typically used in plumbing applications. Polyvinyl Chloride Pipe is the third most widely produced plastic in the world behind only polyethylene and polypropylene. Wikipedia quotes that PVC is "cheaper and stronger than more traditional alternatives such as copper or ductile iron. It can be made softer and more flexible by the addition of plasticizes, the widely used Phthlates. In this form, it is used in clothing , upholstery, and…
3. What are polymers? Polymers are substances made up of atoms with the atoms arranged in repeating patterns.…
1-Chloropentane 4. 1-Chloro-1-pentene 2. 2-Chloropentane 5. 2-Chloro-1-pentene 3. 1,2-Dichloropentane *7. Sandwich bags is typically made of: a. high density Polyethylene b. Polystyrene c. Polyvinylchloride d. Low density polyethylene 8. What is the IUPAC name for this compound?…
the polyaddition reaction, which is a special case of polycondensation, with the difference that the reaction product is exclusively the polymer. In the classical polycondensation reactions, the products are: the polycondensation polymer and a low molecular weight (MW) compound (water, alcohols, and so on). The fact that in the polyaddition reactions the product is only the polymer is of great technological importance, especially for the purity and the morphology of the resulting macromolecular…
2. We discussed how polymer linking and structure contribute to its properties. How would you expect the density, elasticity, and rigidity of a polymer that is branched to compare to one that is linear?…
Polyvinylpyrrolidone (PVP) is a synthetic polymer made from a monomer N_ vinylpyrrolidone. Its known as Povidone in the USP. PVP has many applications in pharmacy, medicine, industrial production and cosmetics (79).…
Polypropylene consist of propylene as the monomer which has three carbons and one double bond between two of those carbon atoms. Polypropylene is manufactured from propylene gas in the presence of a catalyst. They are widely used for pipes, containers and packaging. Nonetheless, Polyethylene is a polymer made of ethylene. Ethylene has two carbon atoms bonded to each other with a double bond. Polyethylene is the basic component in making bottles, bags and fibres. Both polypropylene and polyethylene are thermoplastics polymers. They are linear polymers at which the chains aligned properly giving a range of molecular weights and arrangement of molecules pack together in variety of configurations. (Michael & David, 2013)…
To keep it as simple as possible, (K.I.S.S.) this topic involves the study of: 1. POLYMERS FROM PETROCHEMICALS & BIOMASS…
Polydien Investigations is a private investigation firm that is located in Raleigh, North Carolina. This agency has over 10 years of experience. Polydien Investigations specializes in domestic affairs, criminal investigations, fraud and insurance, computer forensics, missing persons, and surveillance. They are licensed, discreet, and experienced. Polydien Investigations is a State of North Carolina Licensed Private Investigator, with license # 4381.…
Which one of the following polymers is consistent with the above description? (A) (B) (C) (D) 2. high density polyethene low density polyethene polychloroethene polyphenylethylene…
Polymers are substances that are made up of many atoms that form in repeating patterns.…
The dichlorotoluenes are halogenated VOCs that can be directly emitted into the atmosphere from industrial processes or be released through combustion chemistry at incinerator sites. They can also be released in the environment through waste water used during production. They are mainly used as intermediates in the manufacture of fungicides, dyes, pharmaceuticals, preservatives, and peroxides. In a survey sponsored by USEPA of 4000 industrial and publicly owned treatment works, two of the dichlorotoluene isomers (2,6-dichlorotoluene and 2,4-dichlorotoluene) were identified in the discharges into water from rubber processing (1 occurance, 314.9 ppb), organic chemical synthesis (14 occurances, 26.7 ppb), and publicly owned treatment works (5 occurances, 40.4 ppb) (Howard, 1997). The highest effluent concentration reported was 1424 ppb in the paint and ink industry (Howard, 1997). When released in the atmosphere, the dichlorotoluenes should degrade by reaction with hydroxyl radicals with a half-life of about 12 days (Howard, 1997), which is significantly longer than the estimated lifetime for toluene of 2 days (Finlayson-Pitts and Pitts, 2000). Their estimated half-lives…
PPV, which is the abbreviated term for phenylenevinylene, has light emitting properties since it has a large conjugated system. This organic molecule is possible to be formed from dichloro-para-xylene which then reacts with methanol and thiolane. The nucleophile would be the thiolane. A good leaving group in this case would be chlorine. After thiolane attacks, it results with dithiolane-xylene. The second step is reaction with sodium hydroxide. The hydroxide it used for deprotonation upon the substituted methyl group. This creates a carbocation. The carbocation attacks another similar monomer in which the thiolane is the leaving group. This creates two thiolanes on one monomer and one thiolane on the other monomer. The monomer with two thiolanes loses one of the thiolanes to form a double bond near the monomer with one thiolane. The mono with one thiolane gets deprotonated and continues the chain. This cannot work without heat. Chlorine itself is not a strong enough base for deprotonation. However, chlorine is a good leaving group, so a Sn2 or Sn1 mechanism can work. The chlorine leaving thus creates a carbocation, but the carbocation can have resonance stability. These…