2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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produced the most oxygen of all three trials. Heat tends to increase the rate of chemical reactions‚ explained in the article Temperature Effects (Introduction to Enzymes) by Chris Jamison. “Like most chemical reactions‚ the rate of an enzyme-catalyzed reaction increases as the temperature is raised. A ten degree rise in temperature will increase the activity of most enzymes by 50 to 100% . Variations in reaction temperature as small as 1 or 2 degrees
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difference between a mixture and a compound. A compound is a substance in which atoms of different elements are chemically held to one another. A mixture is a substance made by combining two or more different materials in such a way that no chemical reaction occurs. A mixture can usually be separated back into its original components‚ a compound cannot. Below are some examples of the differences between each. Compounds •Compounds are pure substances. •They are made up of two or more elements combined
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Metals and Halogens reactions Elements such as fluorine‚ chlorine‚ bromine‚ iodine‚ and astatine belong to Group 7‚ Halogens. At room temperature‚ fluorine is a yellow gas‚ chlorine is a pale green gas‚ bromine is a red liquid‚ and iodine is a purple solid. Astatine is a radioactive element‚ therefore it exists only in small amounts. All the halogens exist in diatomic molecules. They have high ionization energies and are the most electronegative elements. Their electron configuration ns2 np5 make
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Economy - overviewzz Philippine GDP grew 7.6% in 2010‚ spurred by consumer demand‚ a rebound in exports and investments‚ and election-related spending‚ before cooling to 3.7% in 2011. The economy weathered the 2008-09 global recession better than its regional peers due to minimal exposure to troubled international securities‚ lower dependence on exports‚ relatively resilient domestic consumption‚ large remittances from four- to five-million overseas Filipino workers‚ and a growing business process
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BIOL2220 Lab 3: Hill Reaction Introduction In 1937‚ Robert Hill discovered that isolated chloroplasts can generate oxygen when they are illuminated in the presence of a suitable electron acceptor‚ even in the absence of carbon dioxide. This finding was a landmark in the study of photosynthesis because it established that the source of the electrons used in the light reactions is water. It also confirmed that the released oxygen is derived from water instead of carbon dioxide. In chloroplasts
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Lab #5: Grignard Reaction – Synthesis of Triphenylmethanol John Kang Chem 152L Performed: 7/20/04 Date submitted: ________________ Lab Partners: Sang Lee‚ Vicky Lai TA: John Stanko Abstract: This experiment explored the synthesis of triphenylmethanol through the use of Grignard reagents. The percent yield of the product was 10% on a relatively humid day. The melting point was calculate to be 127.2oC with a literature value of 162oC. An IR spectrum of the product was taken and used
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Potassium Iodide Deionized Water Filter Paper Charcoal Matches Equipment- Clean dry spatula Small Beakers Glass stirring rod Ring stand Funnel Tweezers Bunsen Burner Small Test Tubes Safety- During this lab we are dealing with some dangerous chemical including Lead Nitrate‚ Potassium Iodide. In this lab you will need to be wearing safety goggles at all times and closed toed shoes and for people that have long hair they need to have it tied back because we will be using a bunsen burner. Also when handling
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Lab #5: Refraction of Light Theory: Refraction can be defined as the bending of a wave when it enters a medium which causes it to have some reduced speed. In terms of light‚ refraction occurs when the ray passes through some medium which slows its speed; such as water or glass. In this instance the ray tends to bend towards the normal of the medium. The amount of bending or refraction which occurs can be calculated using Snell’s Law (). Objective: To measure the index of refraction of Lucite
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Purpose: To find out the percent yield of copper in the reaction between copper sulfate (CuSO4) and Iron (Fe). Materials: Balance 100-mL beaker 250-mL beaker Bunsen burner Copper sulfate crystals Glass stirring rod 100-mL graduated cylinder Iron filings Ring stand and ring Wire gauze Procedure: 1. Record mass of clean 100-mL beaker. 2. Add 8.0 grams of copper sulfate crystals to beaker. 3. Add 50.0 milliliters of distilled water to the crystals. 4. Put wire gauze on ring on ring
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