between (n-1)d &ns orbital as a result both (n-1)d &ns electrons take part in bond formation. The highest oxidation state of an element is equal to number of unpaired electrons present in (n-1)d &ns orbital. Transition elements have high enthalpy of atomization/ sublimation Because of large number of unpaired electrons in their atoms‚ they have stronger interatomic interaction and hence strong metallic bonding is present between atoms. Most of transition elements are paramagnetic due
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the molar enthalpy of the NaOH(aq) using the data obtained from this experiment. Show all your work. Answer: Specific heat capacity: 4.19 J/g∙°C 50.0 ml of 1.0 mol/L NAOH Initial temperature: 23.9 °C Final temperature: 32.9 °C Change in temperature: 9 °C Q = mc∆t = (80g)(4.19 J/g∙°C)(9°C) = 3016.8 J or 3.0168 kJ ∆rH = n∆rHm 3.0168 kJ = (0.05 mol) (∆rHm) ∆rHm = 60 kJ/mol (2 marks) 2. The accepted molar enthalpy of neutralization
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THERMODYNAMICS - THEORY A control volume may involve one or more forms of work at the same time. If the boundary of the control volume is stationary‚ the moving boundary work is zero‚ and the work terms involved are shaft work and electric work. Another work form with the fluid is flow work. Flow Work (Flow Energy) A Flow Element Flow Work with Imaginary Piston Click to View Movie (68 kB) Work is needed to push the fluid into or out of the boundaries of a
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at the surface of the adsorbent. 7. 8. Sorption: When adsorption and absorption take place simultaneously‚ it is called sorption. Enthalpy or heat of adsorption: Adsorption generally occurs with release in energy‚ i.e.‚ it is exothermic in nature. The enthalpy change for the adsorption of one mole of an adsorbate on the surface of adsorbent is called enthalpy or heat of adsorption. 9. Types of adsorption: Get the Power of Visual Impact on your side Log on to www.topperlearning.com
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heat‚ depending on the reacting substances. Calorimetry is the process of measuring the heat flow between a system and its environment. The device used to measure this heat transfer is called a Calorimeter. The measurement of this heat is called the enthalpy of the reaction (∆H). There are two types of calorimeter. The first is a bomb calorimeter where the reaction takes place at constant volume. The other type is the coffee cup calorimeter‚ wherein the pressure is held constant while the reaction
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Assignment Chapter 6 Concept Explorations 6.29. Thermal Interactions Part 1: In an insulated container‚ you mix 200. g of water at 80ºC with 100. g of water at 20ºC. After mixing‚ the temperature of the water is 60ºC. * a. How much did the temperature of the hot water change? How much did the temperature of the cold water change? Compare the magnitudes (positive values) of these changes. 200g of water at 80°C = hot water 100g of water at 20˚C = cold water After mixing the temperature is
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Shinhye Lee Chem101 4.16 Specify what ions are present upon dissolving each of the following substances in water: a) MgI2(aq) -> Mg 2+ (aq) +2OH-(aq) b) Al(NO3)3(aq) -> Al3+(aq)+3NO3- (aq) c) HCLO4(aq) -> H+ (aq) + ClO4- (aq) d) NaCH3COO(aq) ->Na + (aq) + CH3COO-(aq) 4.22) In each reaction‚ the precipitate is in bold type. a) Ni(NO3)2 (aq) +2NaOH (aq) ->+2NaNO3(aq) + NiOH2 (s) b )No precipate‚ therefore‚ no reaction. c) Na2S(aq) + CuCH3COO (aq) -> CuS(s) + 2NaCH3COO
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I. Objective The first objective of the measurement of thermal conductivity & one-dimensional heat conduction experiment was to identify three different metal specimens by comparing their experimentally determined thermal conductivities to known thermal conductivity values of existing metals. The second objective of the experiment was to establish a connection between the thermal conductivities & temperatures of the metal specimens. Thirdly‚ the contact resistance of the interfaces between
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Lanthanides and Actinides The lanthanides and the actinides make up the f block of the periodic table. The lanthanides are the elements produced as the 4f sub level is filled with electrons and the actinides are formed while filling the 5f sub level Some significant similarities and differences between lanthanides and actinides are observed. The two rows that are generally placed underneath the main periodic table are called the lanthanides series and the actinides series. These two rows are produced
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Seminar Report On Theoretical Analysis for Controlling the System Temperature by using phase change material (PCM) Presented by Mr.Ajinkya R. Patil INDEX 1. INTRODUCTION………………………………………………………...1 2. STATE OF THE ART OF PCM…………………………………………2 3.1 PCM CHARACTERISTICS………………………………………...2 3.2 PCM CLASSIFICATION…………………………………………...5 3.3 PCM PROPERTIES………………………………………………...3 3. THERMOPHYSICAL PROPERTIES DETERMINATION…………5 4.4 LONG TERM STABILITY…………………………………………5
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