Aqueous Acid/Base Chemistry Resources: Harris ‘Quantitative Chemical Analysis’ Review: Pure water has a pH = 7 Autodissociation: H2O (( H3O+ + OH- K = [H3O+][OH-]/[H2O] -log[H3O+] = 7 [H3O+] = 10-7 M = [OH-] [H2O] = 55.56 M K = 1.8 x 10-16 ; pKa = 15.74 pKa is the acid dissociation constant; low pKa (strong acid‚ high pKa (weak acid we can also write Kw = [H3O+][OH-] Kw = 10-14 In water‚ pH + pOH = 14 pH scale Strong
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Name: Citric acid Chemical Name: 2-hydroxypropane-1‚2‚3-tricarboxylic acid Chemical Formula: C6H8O7 Chemical Structure: pH: 4.18‚ 3.90‚ 3.57 Classification: Weak acid Uses: It is a natural preservative/conservative and is also used to add an acidic or sour taste to foods and drinks. It is also used mainly as an acidifier‚ as a flavoring‚ and as a chelating agent. Name: Vinegar acid Chemical Name: Acetic acid or ethanoic acid Chemical Formula: C2H4O2 Chemical Structure:
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expected melting point. After its temperature reached the plateau‚ the temperature increment was set at 1°C per minute‚ and the melting point range of 152°C-154°C was recorded. After standardizing the melting device‚ a small sample of unknown carboxylic acid was placed in a capillary tube‚ and an arbitrary plateau of 200°C was set. When the sample started to melt at 150°C‚ another capillary tube containing a small amount of unknown sample was placed in the melting device‚ and the plateau was set to 135°C
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EXPERIMENT 2 ACID DISSOCIATION CONSTANT OF AN INDICATOR DYE OBJECTIVES Using spectrophotometric method: determine the wavelengths at which the acid and base forms of the dye in aqueous medium exhibit maximum absorption; determine the molar absorptivities of the acid and base forms of the dye and estimate an unknown concentration of the dye in solution using the Beer-Lambert’s Law; and determine the acid dissociation constant of the indicator dye. THEORY The absorption or reflection of
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18.1.4 – 18.1.6 CALCULATIONS INVOLVING ACIDS AND BASES Review of Important formulas pH = ‐ log10[H+] [H+] = 10‐pH pKa = ‐ log10 Ka Ka = 10‐pKa pOH = ‐ log10[OH‐] [OH‐] = 10‐pOH pKb = ‐ log10 Kb Kb = 10‐pKb The ionic product of water = Kw = [H+] x [OH‐] = 1.0 x 10‐14 mol2 dm‐6 at 298 K The expression varies with temperature
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This paper is an analysis conducted on Nucleic Acids through a variety of tests specifically‚ Dische‚ Murexide‚ Wheeler-Johnson and Phosphate Tests in order to exemplify structural features of nucleic acids as well as identify the principle involved in each chemical test. Different procedures and different test compounds were applied‚ and results were noted as for changes in colors of precipitates or solutions. For Dische Test‚ light blue was obtained for RNA and dark violet for DNA. For Murexide
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Affects of Hydrogen Peroxide Equivalents on Green Synthesis of Adipic Acid. Andrew R. Glessman*‚ Chase W. Turner‚ Audra Cokain‚ Jacob Kindred‚ Darryl Watkins Department of Chemistry and Chemical Biology‚ IUPU‚ 402 N. Blackford St‚ Indianapolis‚ IN 46202 aglessma@umail.iu.edu April 25‚ 2014 Figure _______________________________________________________________Abstract- The synthesis of adipic acid has been a growing topic of discussion due to the harmful impact it has on the environment
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Extraction of R’-NH2 For both of the organic acid and organic base extraction‚ the addition of the respective inorganic acid or inorganic base (HCl or NaOH) to the three-component mixture caused an immiscible appearance of the solution in the separatory funnel. By briskly shaking the separatory funnel with the mixed components created a build up of pressure which was released through the stopcock forming small disappearing bubbles within the tip of the separatory funnel. Once the funnel was placed
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Jarrett Sears Dr. Hummel Chem 121 2/7/13 A Chemical Reaction between Tin and Nitric Acid Introduction: Finding the products made from the components of tin metal and nitric acid is the ultimate objective of this lab; the formula of the products will be found in the CRC handbook thereafter. Procedure: First‚ obtain a clean crucible‚ and heat it under a Bunsen burner until it is as hot as possible‚ about 15 minutes within a fume hood unit. The Bunsen burner will be used under the fume
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How Acetylsalicylic Acid was Discovered Acetylsalicylic Acid in its earliest form was a powder for the bark and leaves of the willow tree. Hippocrates‚ who lived sometime between 460 B.C. and 377 B.C‚ founded it. This “Miracle Drug” that was able to relieve pains was later looked into with further detail by Johann Buchner. He isolated a tiny amount of bitter tasting yellow‚ need- like crystals‚ and called salicin. By 1829 French Chemist Henri Leroux had improved the extraction procedure to
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