reactions – curly arrows‚ chemical reactions‚ substitution‚ elimination‚ etc 3) Delocalization and conjugation – theory of resonance‚ structure of alkenes‚ allyl‚ vinyl systems. 4) Acidity‚ basicity and pKa 5) Conformational Analysis - Cyclohexane 6) Stereochemistry – regioselective‚ stereoselective‚ stereospecific 5 Examples of Topics covered for Revision Quiz 1 (not limited to the topics below) 1) 2) 3) 4) 5) 6) 7) 8) Acids and Bases Conformations of Alkanes and Cycloalkanes Alcohols and Alkyl halides
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Chapter 17—Alcohols and Phenols SHORT ANSWER Drawing Instructions: Draw structures corresponding to each of the given names. 1. Draw: cis-4-tert-butylcyclohexanol ANS: 2. Draw: 3-methyl-2-buten-1-ol ANS: 3. Draw: 2-phenyl-2-propanol ANS: 4. Draw: glycerol ANS: 5. Draw: 2‚ 4‚ 6-trinitrophenol ANS: IUPAC Naming Instructions: Provide proper IUPAC names. 6. Name: ANS: (E)-2-ethylbut-2-en-1-ol 7. Name: HOCH2CH2OH ANS:
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starting material into each of two small labeled test tubes. Take two more small labeled test tubes and place 4 or 5 drops of your 4-methylcyclohexene product in each of them. Take one tube from each group‚ and count how many drops of the provided bromine in methylene chloride solution it takes before the red color remains upon contact with the liquid sample. Record this information. Test the remaining two liquids in a similar way using the potassium permanganate
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Formation of an Alkene by Alcohol Dehydration Lab Report Balanced Chemical Equation for the Main Reaction Mechanism The acid-catalyzed dehydration of secondary and tertiary alcohols involves non-isolable carbocation intermediaries. In the first step of the of the reaction mechanism below‚ a phosphoric acid catalyst adds a proton to the oxygen atom of the alcohol to form an oxonium ion. The OH is converted to a better leaving group as the positive charge on the oxygen weakens the carbon-oxygen
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(Mg + CuSO4 MgSO4 + Cu). In this example‚ magnesium is above copper in the activity series so it is able to displace copper. An example of an anion replacement reaction is the reaction of bromine and potassium iodide‚ which produces potassium bromide and iodide (Br2 + 2KI 2KBr +I2). In this example‚ bromine replaces iodide in the potassium iodide
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SCH 4U1 FINAL EXAM REVIEW ATOMIC STRUCTURE AND MOLECULAR ARCHITECTURE 1. Describe the wave mechanical model of the atom. 2. Write the ground state electron configuration for Br. 3. Explain why the first ionization energy for Ne is significantly greater than Na. 4. Distinguish between ionization energy and electronegativity. 5. How does VSEPR Theory account for the fact that the bond angle in H2O is less than NH3? 6. Which of the following molecules are polar? Include diagrams
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Elemental Analysis 1Professor‚ School of Chemical Engineering‚ Chemistry and Biotechnology‚ Mapua Institute of Technology; 2Student‚ CHM146L-B31‚ School of Chemical Engineering‚ Chemistry and Biotechnology‚ Mapua Institute of Technology [pic] ABSTRACT Elemental analysis of organic compounds determine the elements present in them but they do not give the actual structure or the functional groups present. Since all organic compounds contain hydrogen and carbon‚ most tests consist of only the
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as the Reduction. In this part of the Redox reaction or in this step‚ it is very important that you already know the Oxidizing and Reducing agent for us to find the half reaction. In this step or part‚ we will also learn how to balance using the addition of electrons in both sides if necessary. After this step we can now write the net ionic equation. There are guidelines that will help you to write the step by step in getting the net ionic equation. + Spectator Ion- You cannot change the charges
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Mechanism for Olefin Polymerization Chain Propagation: Cossee-Arlman Mechanism = good basic mechanism. Cossee et al.‚ J. Catal.‚ 1964‚ 3‚ 80 & 99. 1‚2-insertion alkene coordination R [M] R [M] [M] R CH2 C H2 [M] R Green-Rooney Mechanism involving metathesis-like step = totally wrong ! CHP CH2P [M] α-elimination [M] H CHP [M] H PHC H [M] R reductive elimination PH2C [M] R alkene coordination R metathesislike process This Mechanism DOES NOT Occur Proposed by Green‚ Rooney
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Chemistry SCH3U Unit 1 Lesson 1 Key Questions 1. List three physical properties and one chemical property of a) an iron nail * conducts heat and electricity well * solid at room temperature * ductile * rusts in water (chemical) b) gasoline * liquid at 20deg C * boils between 20 and 200 degrees Celsius * not soluble in water * flammable in the presence of oxygen (chemical) 2. People in a workplace should have access to MSDS sheets so that * chemicals
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