Often projects find that orange juices made from frozen concentrated orange juice (FCOJ) have the highest vitamin C levels as compared to freshly squeezed or not-from-concentrate (NFC) juices. This is probably due to the fact that vitamin C degrades over time in fresh and NFC, but doesn't degrade as much in FCOJ due to it being frozen until reconstitution. If one is comparing a NFC product that has been stored for about 3 weeks versus a newly reconstituted FCOJ, the FCOJ would almost certainly have a higher vitamin C concentration. Also another thing to consider is if the FCOJ is reconstituted to the same strength as fresh or NFC. If one doesn't add enough water, then the vitamin C (and other compounds) would be more concentrated. Another consideration is that the vitamin C content changes through the harvest season and orange variety also plays a part. Since most FCOJ is blended to a larger extent than some NFCs, it is entirely possible that the NFC is produced from a variety/season that has a lower vitamin C content.
According to Nagy and Smoot, temperature and storage time affects the percent of vitamin C content of orange fruits and orange juice. Different varieties of oranges also have different levels of vitamin C. The mid-season variety, Pineapple Orange had the highest levels, followed by the main early-season variety, Hamlin Orange. The late-season Valencia Orange had the lowest vitamin C content. Additionally, it was found that the longer the Valencia Orange fruit stayed on the tree, the lower the vitamin C level. (Additional details on these orange varieties can be found from links in The Story of Florida Orange Juice - From the Grove to Your Glass.) Nagy and Smoot also found that in orange juice containers, vitamin C loss was due to oxidation by a residual air layer trapped within the container during processing. The loss was faster in the