The reaction of Hydrogen Peroxide and Iodide ions in an acidic medium: 3 I-(aq) + H2O2(aq) + 2 H+(aq) I3-(aq) + 2 H2O(l) Step 1. H2O2(aq) + I-(aq) IO-(aq) + H2O(l) Step 2. IO-(aq) + H+(aq) HOI(aq) Step 3. HOI(aq) + 2 I-(aq) + H+(aq) I3-(aq) + H2O(l) In this reaction the three iodide ions are oxidised to form the triiodide ion. This occurs in three steps. Firstly‚ the peroxide molecule oxidises a single iodide ion‚ to form a hypoiodite ion‚ and a molecule of water. This is the
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the reducing solution is potassium iodate solution and the oxidizing solution is sodium thiosulphate solution. Potassium iodate solution which is an oxidizing agent is added into an excess solution of acidified potassium iodide. This reaction will release iodine. Potassium iodide is acidified with sulphuric acid and the iodine released quickly titrated with sodium thiosulphate until it become light yellow. The iodine then detected with starch solution and it turn into dark blue solution and titrated
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Solubility Rules Chart Negative Ions (Anions) + Positive Ions (Cations) = Solubility of Compounds in water Example any anion + Alkali Ions (Li+‚ Na+‚ K+‚ Rb+‚ Cs+‚ Fr+) = soluble Sodium fluoride‚ NaF‚ is soluble any anion + hydrogen ion [H+ (aq)] = soluble hydrogen chloride‚ HCl‚ is soluble any anion + ammonium ion (NH4) = soluble ammonium chloride‚ NH4Cl‚ is soluble nitrate NO3- + any cation = soluble potassium nitrate‚ KNO3‚ is soluble acetate (CH3COO-) + any cation (except
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Top of Form Bottom of Form Chemical Compound Formulas Chemistry is the study of the composition of matter and its transformation. A substance can be considered matter with definite properties that establishes its identity. The tremendous number of chemical compounds has been categorized into numerous categories. A broad classification distinguishes between inorganic and organic compounds. Organic compounds are carbon based. Inorganic compounds exclude compounds exclude compounds based on carbon
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EXPERIMENT TWENTY Qualitative Analysis of Anions Analysis of Solutions Containing the Ions Cl-‚ Br-‚ l-‚ SO42-‚ CO32-‚ and NO3- This experiment continues the qualitative analysis begun in Experiment 19. Here we will be analyzing solutions to determine the presence of anions. The same techniques that were used for the cation analysis must be used for the anions. If you have not carried out Experiment 19‚ read the introductory section before starting this experiment. The major difference
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I2. The brown iodine solution can be reduced by vitamin C (ascorbic acid) to form colourless iodide ions. However‚ I2 solution is not normally prepared directly by dissolving iodine in water because iodine is too volatile so it is almost impossible to avoid loss while the solution is being prepared. Therefore iodine is prepared in situ by mixing pure potassium iodate (KIO3 ) and potassium iodide (KI) in acidified medium. IO3- + 5I- + 6H+ → 3I2 + 3H2O The excess iodine
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produce iodide ion (I-) and dehydroascorbic acid‚ as shown in the following equation: [IMAGE] + I2(aq) -----------> + 2H+(aq) + 2I-(aq) Ascorbic acid (Vit. C) Dehydroascorbic acid However‚ since iodine is only slightly soluble in water‚ ascorgic acid should not be titrated directly by a standard iodine solution‚ since the end point of titration is not o obvious. Instead‚ back titration will be employed. The titration of a reducing agent with iodine to produce iodide ion is
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The stopper is removed carefully from the conical flask and 2 mL of the manganese sulfate solution is added‚ discharging the reagent from the tip of a pipette put well below the water surface. Stopper is replaced. 3. Similarly‚ 2 mL of the alkaline-iodide solution is introduced. 4. The stopper is placed in the bottle‚ be sure that no air becomes entrapped. Some overflow may occur. The content is mixed thoroughly by inversion and rotation. Manganese hydroxide is precipitated and will settled on standing
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Determination of Chlorine and Iodine in Water I. Introduction The purpose of this laboratory was to determine the amount of chlorine and iodine in a sample of water by titration using a starch indicator and to standardize a sodium thiosulfate solution. Chlorine is added to municipal water supplies to purify it enough to become safe to drink. Iodine is also added to water when people camp or go hiking in the back country where they cannot bring purified water along. Chlorine and iodine are
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ELECTRONEGATIVITY This page explains what electronegativity is‚ and how and why it varies around the Periodic Table. It looks at the way that electronegativity differences affect bond type and explains what is meant by polar bonds and polar molecules. If you are interested in electronegativity in an organic chemistry context‚ you will find a link at the bottom of this page. What is electronegativity Definition Electronegativity is a measure of the tendency of an atom to attract a bonding pair
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