August 28‚ 2009 [PROBLEM SET FROM R. CHANG TEST BANK] Chapter 16 Acid-Base Equilibria and Solubility Equilibria Student: ___________________________________________________________________________ NOTE: A table of ionization constants and Ka’s is required to work some of the problems in this chapter. 1. In which one of the following solutions will acetic acid have the greatest percent ionization? A. B. C. D. 2. Which one of the following is a buffer solution? A. B. C. D. E. 3. 0.40 M HCN and
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Chapter 1 Chemical Reactions and Equations Q.1. Why should magnesium ribbon be cleaned before burning in air ? Ans: Magnesium ribbon is a very reactive metal. When stored it reacts with oxygen to form a layer of magnesium oxide on its surface. This layer of magnesium oxide being a stable compound prevents further reaction of magnesium with oxygen. The magnesium is cleaned before burning in air to remove this layer so that the metal can be exposed to air properly. Q.2. Write the balanced
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1. (a)Correct the following statements. (i) The melting points of crystalline and amorphous solids are not definite. The melting point of an amorphous solid is not definite. OR The melting point of a crystalline solid is definite. P Ps X solute . Ps P Ps The equation for relative lowering of vapour pressure when solute remains normal is X solute P (iii)The degree of ionization decreases with dilution. The degree of ionisation increases with dilution. (iv) Tertiary butyl halide
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-CATIONS and ANIONS- Cations are positive charged ions. A cation has fewer electrons than protons. Anions are negatively charged ions. An anion has more electron than protons. The nature and magnitude of charge on ion depend on the position of an element in the periodic table. In forming an ion‚ an atom of a main group element loses gains electrons to obtain the electronic configuration of the noble gas closest to it in the periodic table. This gives the ion on especially stable electronic arrangement
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INTRODUCTION: Carbohydrates are the product that made up from carbon‚ hydrogen and oxygen. Carbohydrates are form by the combination of carbon dioxide and water molecules. The carbohydrates contain two specific functional group in it which is the hydroxyl groups and carbonyl groups.A reducing sugar is a type of sugar with is an aldehyde group.This means that sugar can act as a reducing agent.The procces of reducing sugar is isomerisation‚example of reducing sugar islactose
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therefore is less reactive than haloalkane towards nucleophilic substitution reaction. 2. Haloalkanes react with KCN to form alkyl cyanide as main product while AgCN form isocyonide. Ans. KCN is‚ predominantly ionic compound and provide cyanide ion : C N in solution. The attack mainly takes place through lone pair of electron on carbon atom due to high electron density and not through nitrogen atom since C-C bond is more stable than C-N bond. AgCN: is mainly a covalent compound therefore‚ nitrogen
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1. Disposing of Waste - Teachers should be aware of the appropriate method of disposal for any chemical used in the school laboratory. When in doubt‚ refer to the MSDS‚ a disposal manual‚ or the source of the chemical. a. Classification of Hazardous Waste The Environmental Protection Agency classifies wastes as: Ignitable: has a flash point below 140°C‚ is an oxidizer‚ or is an ignitable compressed gas. Corrosive: has a pH equal to or below 2.0 or a pH equal to or greater than 12.5. Reactive:
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In this experiment‚ the objective is to successfully perform an SN1 reaction to determine the reactivity of tert-butyl chloride‚ through the usage of sodium iodide/silver nitrate reagents and to synthesize tert-butyl chloride. The tert-butyl chloride was synthesized through the use of separation (aqueous and organic layers) and distillation. Tert-butyl chloride is the alkyl halide which is being synthesized throughout the course of the experiment. Alkyl halides are derived from alkanes. Once an alkane
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ratios (solute to solution) x a million (106). In this sense‚ they are similar to wt %‚ which could be thought of as parts per hundred (although nobody uses this term). Other variations on this theme include: ppt – parts per thousand (used for common ions in sea water) ppb – parts per billion (used for heavy metals and organics) ppt – parts per trillion (used for trace metals and trace organics) The following table summarizes common mass ratios for solutions and solids. Unit Solutions Solids ppm mg/L
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though there is no visible reaction initially. Shortly thereafter‚ the liquid suddenly turns to a shade of dark blue. This clock reaction uses ammonium persulfate to oxidize iodide ions to iodine. 2I- (aq) + S2O82- (aq) → I2 (aq) + 2SO42- (aq) Subsequently‚ sodium thiosulfate is used to reduce iodine back to iodide before the iodine can complex with the starch to form the characteristic blue-black color. I2 (aq) + 2S2O32- (aq) → 2I- (aq) + S4O62- (aq) An important factor that affects
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