2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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Aim: The aim of my experiment is to find out the rate of reaction between Hydrochloric acid (HCL) and Magnesium (Mg) in different temperatures. The products that will be formed are Magnesium Chloride (MgCl2) and Hydrogen (H2). Prediction: I predict that as the temperature increases the rate of reaction also increases. To further explore the fact I further predict that the rate of reaction will double for every 10° C rise in temperature. I further predict as the temperature rises by 10° C the rate
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Introduction The Diels-Alder Reaction is a reaction used in organic chemistry that builds rings very efficiently (1)‚ this cycloaddition process allows for the stereoselective formation of cyclohexene rings possessing as many as four contiguous stereogenic centers (3). This reaction occurs without intermediates‚ in a single step‚ which explains the stereospecificity due to substituents not being given the chance to “switch around”. (1)These six membered rings are synthesized by reacting a dienophile
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Some metals react with acids while others do not. In this experiment‚ students will perform 2 reactions: aluminum/zinc with excess 6M hydrochloric acid and aluminum-zinc alloy with excess 6M hydrochloric acid. The purpose of this experiment is to determine the atomic mass of each metal and the percent composition of a known mass aluminum-zinc alloy by determining the moles of H2 gas formed. Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g) 1 mole of H2(g) is produced for every 1 mole of Zn(s) 2. 2Al(s)
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The Effect of the Concentration of Sulphuric Acid on the Reaction Rate with Magnesium Sarah Cain SCH 4UB Mr. Lankin April 1‚ 2009 Introduction The nature of the problem is to design an investigation that examines a variable affecting the reaction rate. In this experiment‚ magnesium will be reacted with different concentrations of sulphuric acid. The reaction is shown by the following chemical equation: H2SO4 (l) + Mg (s) → MgSO4 (aq) + H2
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Factors affecting the rate of reaction between a metal and an acid The rate of a reaction can be measured by the rate at which a reactant is used up‚ or the rate at which a product is formed. The temperature‚ concentration‚ pressure of reacting gases‚ surface area of reacting solids‚ and the use of catalysts‚ are all factors which affect the rate of a reaction. Individual properties of substances also affect reaction rates. The scope of these properties is broad and there are few generalizations
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The purpose of the experiment was to perform an electrophilic addition reaction by the bromination of cinnamic acid. The product of this reaction is 3-Phenyl-2‚3-dibromo propionic acid‚ which is purified by recrystallization. Cinnamic acid (3-phenylprop-2-enoic acid) is an unsaturated carboxylic acid. The electron rich π cloud (see Figure 1) in the double bond of this structure is nucleophilic and can be considered a Lewis base. It can therefore be saturated by the addition of a halogen to the double
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Patrick Combs’ Major in Success proves to be an extraordinarily valuable tool for college students interested in deriving the most from their college experience. The book contains ample advice for facilitating a sometimes confusing time as an undergraduate student while managing to fire up dreams that can translate into amazing post-graduation opportunities‚ specifically jobs. Combs divides the book into sections‚ which include the Dream Job and the Action Plan. Each of these two parts encourages
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Title : Expt.1 Determination of the enthalpy (heat) of reaction of a monobasic acid with sodium hydroxide Experiment no : 1 Experiment title : Determination of the enthalpy (heat) of reaction of a monobasic acid with sodium hydroxide Objectives: 1) To understand the enthalpy chemistry. 2) To determine the calorimeter constant. 3) To determine the enthalpy reaction of acid-base reactions. 4) To study the exothermic reaction. Apparatus and Materials : * Dewar flask‚ stopwatch
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China Rosin Maleic Acid Glycerol Ester Industry 2014 Market Research Report The report firstly introduced Rosin Maleic Acid Glycerol Ester basic information included Rosin Maleic Acid Glycerol Ester definition classification application industry chain structure industry overview; international market analysis‚ China domestic market analysis‚ Macroeconomic environment and economic situation analysis and influence‚ Rosin Maleic Acid Glycerol Ester industry policy and plan‚ Rosin Maleic Acid Glycerol
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