Richard F. Daley and Sally J. Daley www.ochem4free.com Organic Chemistry Chapter 2 Introduction to Organic Nomenclature and Functional Groups 2.1 Drawing Organic Structures 73 2.2 Alkanes 77 2.3 Structural Isomerism 77 2.4 IUPAC Nomenclature 79 2.5 Naming Alkanes 80 2.6 Naming Cycloalkanes 87 2.7 Naming Complex Alkyl Groups 2.8 Functional Groups 97 2.9 Naming Alkenes and Alkynes 2.10 Naming Alkenes‚ Part II 108 2.11 Arenes 109 2.12 Organohalogens 113 2.13 Using Molecular
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dimethoxybenzene by reacting 1‚ 4 dimethoxybenzene with tertiary-butyl alcohol in the presence of sulfuric acid as a Lewis acid catalyst. The reaction will occur via the Friedel-Crafts alkylation mechanism‚ and involves the attack of the aryl group at the electrophilic trimethylcarbocation. The resulting product will be recrystallized using methanol and characterized using IR spectroscopy and melting point analysis. Materials Used: 1 beaker‚ 400-mL sand bath ice for ice bath Erlenmeyer flask‚ 25-mL several
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the weight and melting point of the final version of the sample. I began the lab with 1.5 grams of the impure acetanilide solute and ended the lab with 0.05 grams of pure acetanilide crystals. The percentage of pure acetanilide I recovered during this lab was 3.33%‚ which is lower than I expected. However‚ the low percentage shows that the impurities within the original impure acetanilide solute were removed. A number of factors could have caused the low yield of pure crystals. The melting
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enone “9” to form the aminopyrimidine “8” then “8” is reduced in the presence of palladium then refluxed for 21 hrs to form amine group which is replaced by nitro group‚ finally they added acid chloride 6 to 17 then the amine group attack the electrophilic carbon (the carbon near to Cl) and eliminate Cl
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ETHERS Classification of Ethers: Symmetrical ethers – two groups attached to O are identical Ex. CH3CH2OCH2CH3 – diethyl ether Unsymmetrical ethers – two groups attached to O are not identical Ex. CH3CH2OCH3 – ethyl methyl ether Physical Properties of Ethers: Ethers have much lower boiling points compared to alcohols of comparable MWs. BPs of ethers increases with increasing MW. BPs of isomeric ethers increase with increasing alkyl chain length. BPs of ethers are about the
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compound. The methods used to achieve this objective were also hot vacuum filtration in order to remove suspended solid impurities‚ and isolating the pure acetanilide. In the next lab‚ percent recovered was obtained through weighing the acetanilide sample as well as comparing its melting point range. In this experiment‚ the sample‚ acetanilide was weighted to be 1.523 grams. The sample appeared to be a pale mixture of brown flakes before it was crushed into small flakes. When boiling the sample with
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Alkyl Halides Alkyl halides are a class of compounds where a halogen atom or atoms are bound to an sp3 orbital of an alkyl group. CHCl3 (Chloroform: organic solvent) CF2Cl2 (Freon-12: refrigerant CFC) CF3CHClBr (Halothane: anesthetic) Halogen atoms are more electronegative than carbon atoms‚ and so the C-Hal bond is polarized. H H μ C + C-l δ δ H The C-X bond is polarized in such a way that there is partial positive charge on the carbon and partial negative charge on the halogen. Dipole moment
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I. Abstract The experiment: Classification tests on Organic Compounds‚ allows the students to be familiarized with different classification tests used for identifying the different classes of organic compounds; examine unknown compounds using appropriate tests; and identify functional group of an organic compound based on the tests performed. Several organic compounds with different functional groups were tested to identify the functional groups present in the compound. n-heptane‚ pentene
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EXPERIMENT 5 - Preparation of Acetanilide Preparation and purification of Acetanilide [pic] Purpose: a) To synthesis acetanilide by reaction of aniline and acetic anhydride. b) To purify acetanilide by crystallization method from water c) Purity check by melting range Equipment / Materials and Hazars: hot plate beakers(150‚250mL) ice stirring rod spatula Büchner
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0 PANJAB UNIVERSITY CHANDIGARH- 160 014 (INDIA) (Estted. under the Panjab University Act VII of 1947-enacted by the Govt. of India) FACULTY OF SCIENCE SYLLABI FOR M.Sc. (TWO YEAR COURSE ) IN CHEMISTRY 1st & 2nd YEAR( Semester System) EXAMINATIONS 2013-2014 --:O:-- 1 OUTLINES OF TESTS‚ SYLLABI AND COURSES OF READING FOR M.Sc. FIRST YEAR (SEMESTER-I) EXAMINATION OF 2013 OBJECTIVE OF THE COURSE To teach the fundamental concepts of Chemistry and their applications. The syllabus pertaining
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