Analysis calculated for C14H8Br2ClN3; Calcd.: %C‚ C‚ 40.67; H‚ 1.95; N‚ 10.16‚ Found: % C 40.70; H‚ 1.99; N‚10.10. IR: υmax./cm-1 3250‚ 3140 (NH2)‚ 3010 (C-H aromatic)‚ 1620 (C=N) and at 1600 (C=C). 1H-NMR (DMSO-d6‚ ppm): δ 7.5-8.5 (m‚ 6H‚ Ar-H ) and at 12.9( 2H‚ s‚ NH2‚ exchangeable with D2O). 13C NMR (DMSO-d6):163‚ 161‚ 149‚ 140‚ 133‚ 135‚ 129.4‚ 129‚ 125‚ 122‚ 120‚ 114. MS: m/z = 417 6‚8-dibromo-2-(4-chlorophenyl)-4-hydrazinylquinazoline (V) Chloro compound III ( 0.01 mol) and hydrazine hydrate
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Lab 2: Infra-Red (IR) - Nuclear Magnetic Resonance (NMR) Exercises In Molecular Spectroscopy - Structural Determination Organic Chemistry II CHEM 2425 Manrique October 30‚ 2012 Alex Wolf Introduction For the purposes of this lab‚ the chemical formula will be given‚ and the degrees of unsaturation can be calculate from the formula (2C+2)-(H+Hal-N)/2. The degrees of unsaturation will give clues as to the structure. A double bond‚ as well as a ring will have one degree of unsaturation each
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Synthesis‚ characterization‚ crystallographic Study and antibacterial activity of sodium butyldithiocarbamate pentahydrate‚ C5H20NNaO5S2 Ayodele T. Odularu a‚ Peter A. Ajibade a‚ Bolhuis‚ A. b a. Department of Chemistry‚ University of Fort Hare‚ Private Bag X1314‚ Alice 5700‚ South Africa. b. Department of Pharmacy and Pharmacology‚ University of Bath‚ United Kingdom. Abstract Synthesis of sodium butyldithiocarbamate pentahydrate‚ C5H20NNaO5S2‚ entailed a one-pot synthesis. The process of synthesis
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Published on Web 05/25/2006 A Solid-State 95Mo NMR and Computational Investigation of Dodecahedral and Square Antiprismatic Octacyanomolybdate(IV) Anions: Is the Point-Charge Approximation an Accurate Probe of Local Symmetry? Michelle A. M. Forgeron and Roderick E. Wasylishen* Contribution from the Department of Chemistry‚ Gunning/Lemieux Chemistry Centre‚ UniVersity of Alberta‚ Edmonton‚ Alberta‚ Canada T6G 2G2 Received January 6‚ 2006; Revised Manuscript Received April 6‚ 2006; E-mail:
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integral is the anti-derivative of a function. In science and medicine there is a machine called the NMR and MRI. NMR stands for Nuclear Magnetic Resonance. In the field of medicine an NMR is better known as an MRI. The concept of using both machines it practically the same. Chemists use a machine called an NMR machine or a Nuclear Magnetic Resonance Machine. By looking at the graphs obtained from an NMR machine it can be used to identify the structure of unknown compounds. Integration is used when looking
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The products will be confirmed using Infrared spectroscopy‚ the chromic acid test‚ 2‚4-DNP test and 13C NMR spectroscopy. The results of this experiment show that camphor was produced during oxidation (0.6576 g). The IR spectrum shows a strong peak at 1740 cm-1 representing a carbonyl compound‚ which was concluded to be a ketone by the 2‚4-DNP test and the deshielded peak at 218.4 ppm in the 13C NMR spectrum. The product of the reduction reaction was isoborneol (0.1591 g). The IR spectrum indicates
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Electron Spin Nuclear Magnetic Resonance (NMR) Spectroscopy Organic Chemistry BCH3015 • Electron spin is quantized. • The spin quantum number ms has only two allowed values: ms = +½ or –½ • The two directions of spin create oppositely spin create oppositely directed magnetic fields. fields. 61 Proton Spin Organic Chemistry BCH3015 62 Nuclear Spin States • A proton (the nucleus of a 1H atom) also possesses spin. For each nucleus having the spin quantum number
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155oC‚ 80% yield. Analysis calculated for C18H11Br2ClN4O2; Calcd.: %C‚ 42.34; H‚ 2.17; N‚ 10.97‚ Found: % C‚ 42.30; H‚ 2.14; N‚ 10.90. IR: υmax./cm-1 3000 (C-H aromatic)‚ 1610 (C=N) and at 1600 (C=C). 1H-NMR (DMSO-d6‚ ppm): δ 2.6 (s‚ 3H‚ CH3)‚ 5.4 (s‚ 2H‚ OCH2) and 7.5-8.2 (m‚ 6H‚ aromatic-H). 13C NMR (DMSO-d6): 185‚ 164‚ 162‚ 150‚ 141‚ 135‚ 133‚ 129‚ 128‚ 124‚ 123‚ 121‚ 117‚ 72‚ 21. MS: m/z = 510 N’-(2-(6‚8-dibromo-2-(4-chlorophenyl)quinazolin-4-yloxy)acetyl)isonicotinohydrazide (X) : A mixture of
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Title: Competing Nucleophiles (Exp 24‚ pp 211-221‚ pp 808-823‚ pp 836-842) Purpose: The purpose of this experiment is to determine the nucleophilic strength of chloride and bromide ions as it reacts with 1-butanol (n-butyl) and 2-methyl-2-propanol (t-butyl alcohol) under SN1 and SN2 conditions. Method: 40 g of ice and approximately 30 ml of sulfuric acid is cautiously added to a 100 mL beaker respectively. Weigh 7.6 g of ammonium chloride and 14.0 g of ammonium bromide and place it in
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Spectra Analysis Organic Chemistry Lab‚ CHEM 369 The University of Tennessee‚ Knoxville Dr. Smith Spectra 1: tert-butyl cyanoacetate Molecular formula: 141/13 = 10 R 11 => C10H10+11 => C10H21 C10H21NO2 – C3H10 = C7H11NO2 DBE: 2(#C - #H/2 - #X/2 + #N + 2)/2 =2(7 – 11/2 – 0/2 + 1 + 2)/2 = 3=> 1 double bond and 1 triple bond Mass spectrum table: m/z fragment |40
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