w w w e tr .X m eP e ap UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education .c rs om *2925136620* CHEMISTRY Paper 3 (Extended) 0620/33 May/June 2012 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number‚ candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use a pencil for any diagrams‚ graphs
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FORENSIC CHEMISTRY FORENSIC CHEMISTRY SUMMARY NOTES |Ensuring accuracy and contamination of samples for analysis – 1a and 1A |Ensuring accuracy and contamination of samples for analysis – 1a and | | |1A (continued) | |Caution must be taken by scene investigators with regard to their tools‚ |
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cyclohexene with water. The formation of product cyclohexene which is reweight and adding of bromine the last reagent for confirming that is alkene known as bromine test which leads to colour changes. Yet this experiment reflects some important discussion and conclusion for the formation of cyclohexene. INTRODUCTION One of the common ways of preparing an alkene is through the dehydration of an alcohol. Cyclohexanol‚ the reagent of this experiment‚ is used in the production of nylon‚ paints‚ plastics
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Product The terminal alkene is the least substituted and therefore the least favored. 3) The starting alcohol consisted of a mixture of stereoisomers. Draw all the possible stereoisomers of 2-methylcyclohexanol. 4) The reaction you carried out is considered to be reversible. Write an equation for the equilibrium constant (Keq) for the reaction in terms of the concentrations of reagents. Give 2 reasons why your reaction favored the formation of alkenes. We were removing
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bond. Both of the reactants are non-polar but there is an induced polarity during the reaction due to the electron-rich site at the double bond‚ which results in bromine acting as an electrophile. In this reaction‚ the cinnamic acid reacts as an alkene. Alkenes are unsaturated hydrocarbons with a carbon-carbon double bond. In a double bond‚ a pair of electrons lies between the carbon atoms in a σ bond and the other pair of shared electrons lie above and below the plane in a π bond. This electron rich
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Polymerization reaCTIONS polymers are high-molecular-weight compounds‚ fashioned by the aggregation of many smaller molecules called monomers. Ex. plastics that have so changed society and the natural and synthetic fibers used in clothing are polymers. Classification of polymers Homopolymers - consist of repeated long chains or structures of the same monomer unit. Ex. PVC(polyvinyl chloride) Copolymers - polymers that consist of more than one molecule. Trimers - molecules consisting
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Part I (20 marks) – Multiple Choice (2 marks each). Use the structure below to answer questions 1-7. 1. How many degrees of unsaturation are found in the above compound? a) 2 2. c) 4 d) 5 e) 6 What term best describes the alkene in the above compound? a) R 3. b) 3 b) S c) Z d) E e) trans What is the configuration of the chirality centres (stereocentres) labelled 1 and 2 in the above compound? a) 1 is R and 2 is S b) 1 is R and 2 is R c) 1 is S and
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Formation of an Alkene by Alcohol Dehydration Lab Report Balanced Chemical Equation for the Main Reaction Mechanism The acid-catalyzed dehydration of secondary and tertiary alcohols involves non-isolable carbocation intermediaries. In the first step of the of the reaction mechanism below‚ a phosphoric acid catalyst adds a proton to the oxygen atom of the alcohol to form an oxonium ion. The OH is converted to a better leaving group as the positive charge on the oxygen weakens the carbon-oxygen
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CLASSIFICATION TESTS A. Acids There are relatively few suitable tests for carboxylic acids. Classification is based mostly upon solubility tests. If the compound is water soluble‚ test the aqueous solution of your compound with pH paper (also check the pH of the original water). If the compound is water-insoluble and it dissolves in 5% (1.5M) sodium hydroxide and 5% NaHCO3 solutions as performed in your solubility tests‚ it can be classified as a carboxylic acid. Establish an equivalence value
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Name Naza Moore ID# 24120389 Lab# 2 Lab instructors Alecia Palmer and Donald Burke Course Instructor Maureen Wilson Lab Title Preparation of cyclohexene from cyclohexanol Aim Preparation of an Alkene by dehydration of an alcohol in the presence of a catalyst. Calculate the percentage recovery of products. Test for purity and identification of products. Abstract Cyclohexene and cyclohexanol are both colourless aromatic compounds. The major difference between the two is the presence
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