Chemistry revision Atoms elements and compounds Atom-the smallest part of an element that can still be recognized as an element Element-a substance made up of only one type of atom. An element cannot be broken down chemically into any simpler substance Nucleus-middle of the atom‚ which contains protons and neutrons Electron-tiny particle‚ which surrounds the nucleus with a negative charge Compound-when two elements react and combine together which contain more than one element. There
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Carbon Compounds Activity 1: Organic Compounds: Are they Useful? Objective: Recognize the uses of common organic compounds. Materials: paper and pen‚ pentel pen‚ manila paper Labels or Pictures of the following products: gasoline‚ acetone‚ kerosene‚ acetic acid‚ LPG‚ ethanol Procedure: 1) With your group mates‚ use the labels/pictures of the materials to answer the following questions: a.) Complete the table about the uses of the compounds. Indicate using a check mark the uses of
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atoms. ▪ General formula is Cn H2n+2 ▪ All alkanes have the ending –“ane” ▪ Any alkyl branches in the carbon chain have the suffix –“yl” ▪ The name of a branched alkane must indicate the point of attachment of the branch. o Alkenes ▪ A hydrocarbon that contains at least one carbon – carbon double bond. ▪ General formula is Cn H2n o Alkynes ▪ A hydrocarbon that contains at least one carbon – carbon triple bond. ▪ General formula is Cn H2n-2 ▪ In
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Through the top of the condenser‚ 14 mL of concentrated sulfuric acid was added drop wise over a period of ten minutes. The addition of the acid created a change in color of the solution to a rustic orange color. The mixture was refluxed for 30 minutes and the solution changed to a faded yellow-orange color. Once reflux was complete‚ a simple distillation was set up‚ with the
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University of Maryland‚ College Park Department of Chemistry and Biochemistry CHEM 231: Organic Chemistry I‚ Fall 2014 The Highlights Bonnie Dixon TA: Courney Love Office: CHM 2130 email: bdixon1@umd.edu email: clove@umd.edu When/Where: Lecture MWF 9 a.m. – 10 a.m. in CHM 1407 Discussion T/H at 12:30 pm‚ 2 pm‚ and 3:30 pm in the CHM 1228 Course Materials: Organic
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Product The terminal alkene is the least substituted and therefore the least favored. 3) The starting alcohol consisted of a mixture of stereoisomers. Draw all the possible stereoisomers of 2-methylcyclohexanol. 4) The reaction you carried out is considered to be reversible. Write an equation for the equilibrium constant (Keq) for the reaction in terms of the concentrations of reagents. Give 2 reasons why your reaction favored the formation of alkenes. We were removing
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bonds). (3) Name the remaining substituents and their numbers as for alkanes and alkenes. CH3 OH H3C CH2-Cl CH3 H 1-chloro-3‚3-dimethyl-2-butanol Ch10 Alcohols (Str and Syn).doc Page1 (4) Cyclic alcohols have the prefix cyclo-‚ and the hydroxyl group is deemed to be on C-1. HO CH2CH3 1-ethylcyclopropanol (5) Alcohols with double or triple bonds are named using the –ol suffix on the alkene or alkyne name. Numbering gives the hydroxyl group the lowest possible number. When
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acts as a leaving group. The product is the trans-alkene present in the product. Figure 2: Mechanism
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Part I (20 marks) – Multiple Choice (2 marks each). Use the structure below to answer questions 1-7. 1. How many degrees of unsaturation are found in the above compound? a) 2 2. c) 4 d) 5 e) 6 What term best describes the alkene in the above compound? a) R 3. b) 3 b) S c) Z d) E e) trans What is the configuration of the chirality centres (stereocentres) labelled 1 and 2 in the above compound? a) 1 is R and 2 is S b) 1 is R and 2 is R c) 1 is S and
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found that the product yielded 1‚2-epoxydihydronaphthalene as well as naphthalene. Introduction In 1990‚ professor E.N. Jacobsen reported that chiral manganese complexes had the ability to catalyze the asymmetric epoxidation of unfunctionalized alkenes‚ providing enantiomeric excesses that regularly reaching 90% and sometimes exceeding 98% . The chiral manganese complex Jacobsen utilized was [(R‚R)-N‚N’-Bis(3‚5-di-tert-butylsalicylidene)-1‚2- cyclohexanediaminato-(2-)]-manganese (III) chloride
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