or nucleophile? Give examples of (i) nucleophiles and (ii) electrophiles. 10. Classify the reactions below: (a) CH3CH2CH=CHCH3 + Br2 CH3CH2CHBrCHBrCH3 (b) CH3CH(OH)CH3 + KOH(alc.) CH3CH=CH2 + KBr + H2O (c) CH3CH2CH2OH + KMnO4 CH3CH2COOH (d) CH3CH2CHBrCH3 + NaOH(aq) CH3CH2CH(OH)CH3 + NaBr(aq)
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NORTHERN CARIBBEAN UNIVERSITY DEPARTMENT OF BIOLOGY‚ CHEMISTRY and ENVIRONMENTAL SCIENCE LABORATORY MANUAL Instructor: Dr. M. Wilson CHEM401: BIOCHEMISTRY for NURSES Prepared by: Oreane Collins CHEMISTRY LABORATORY REGULATIONS AND SAFETY PRECAUTIONS Reference: http://www.sciencebyjones.com/safety_rules.htm Thanks to the Flinn Scientific Safety Rules for much of the below. General Guidelines 1. Conduct yourself in a responsible manner at all times
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Catalysis: Midterm Review LECTURE 1: Sept 6th 2012 What is catalysis‚ Importance of catalysis‚ Industrial relevance‚ presentation of the course What is Catalysis: Catalyst: * catalyst is substance that increases the rate at which a chemical reaction approaches equilibrium‚ but is not consumed in the process * not reagent or product; noted above equation arrow * participates in kinetic equations‚ but not in eq constant Catalytic Cycle: * succession of chemical changes
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ORGANIC CHEMISTRY Carbon atoms: * Carbon-carbon bonds are not easily broken * Each carbon atom forms 4 covalent bonds * The C-H bond is almost non-polar Classifying organic compounds: * Number of carbon atoms in longest chain: meth‚ eth‚ prop‚ but‚ pent‚ hex‚ hept‚ oct‚ non‚ dec * If it is a branch: -yl; di‚ tri or tetra means there is more than one branch‚ ethyl means there are 2 carbons coming off the branch * If it is a ring of carbons put cyclo at the front of the
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Heptane • Water • Potassium Permanganate • Iodine • 2 test tubes • 4 small flasks Method: (Wear safety specs and lab coats) • Prepare 4 small flasks containing: • A Heptane • B A weak solution of potassium permanganate‚ made by putting a few crystals of KMnO4 in 100 ml of water. Dilute this with more water until it is the same colour as D • C Water • D Iodine in heptane. Dissolve a few crystals of iodine in heptane until the colour in the same as in B Then (in a fume cupboard): • 1. Mix a little of A and
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3/22/2012 ARYL HALIDES 2. displacement reactions of diazonium salts ARYL HALIDES General formula: Ar–X where X = F‚ Cl‚ Br or I Examples Structure: C-X bonds are shorter and stronger Bond C-Cl C-Br Ar-X 1.69 A° 1.86 A° R-X 1.77 1.91 Dipole moments are unusually small. Bond C-Cl Preparation: 1. electrophilic aromatic substitution – useful only if one product is obtained C-Br Ar-X 1.7 D 1.7 D R-X 2.10 D 2.15 D Dipole moments may cancel out depending on the geometry of the
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SSN COLLEGE OF ENGINEERING DEPARTMENT OF CHEMICAL ENGINEERING V Semester – CH 2307 TECHNICAL ANALYSIS LAB -2010 INDEX SHEET CYCLE ONE Date of Condn. Date of Subn. Sign 1 Estimation of COD of the given sample of water. 2 Estimation of Manganese in the given pyrolusite ore. 3 Estimation of Magnesium by EDTA method. 4 Estimation of purity of drug using pH meter. 5 Estimation of Ammonia in ammonium salts. 6 Polarimetric estimation of sugar
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= _____38.4_____ Page 2 5. Write the names of the chemicals shown by their formulas/or the formulas from the given names. a) BaCl2 ____barium chloride_____ b) KMnO4 __potasium permanganate c) H2SO4 ____sulphuric acid______ d) H2O ______hydrogen oxide____ e) AgNO3 ____silver nitrate______ f) Sodium bicarbonate ______Na2CO3____ g) Nitric acid _________HNO3________
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Naming Chemical Compounds PART A Name the following 1 S Sulfur 2 Sb Antimony 3 N2 Dinitrogen 4 PO43- Phosphate 5 Au Gold 6 Rb Rubidium 7 LiCl Lithium Cloride 8 AlBr3 Aluminum (III) Bromide 9 KMnO4 Potassium Manganate (VII) 10 Cu(OH)2 Copper (II) Hydroxide 11 FeSO4 Iron (II) Sulfate 12 NH4Cl Ammonium Chloride 13 ZnCO3 Zinc Carbonate 14 SnF2 Tin (II)Fluoride 15 MgSO4 Magnesium Sulfate 16 MnO2 Manganese (IV) Oxide 17 Ca3(PO4)2 Tricalcium Phosphate 18 NaOH Sodium Hydroxide
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SEMI – MICRO QUALITATIVE ANALYSIS OF SIMPLE INORGANIC SALT _______________________________________________________________ CATIONS: Pb2+ ‚Hg2+ ‚Cu2+ ‚Cd2+ ‚ Ag+ ‚ Fe2+ ‚ Fe3+ ‚ Al3+ ‚ Zn2+ ‚ Mn2+ ‚ Co2+ ‚ Sr2+ ‚ Ba2+ ‚ Mg2+ ‚ NH4+ ANIONS: CO32- ‚ S2- ‚ SO32- ‚ SO42- ‚ NO2- ‚ NO3- ‚ Cl- ‚ Br2- ‚ PO43- ‚ CH3COO- _______________________________________________________________ PRELIMINARY TESTS 1. Note the state (amorphous or crystalline) and colour of salt. 2. Test the solubility of the salt in
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