SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION Methodology The following stock solutions were prepared: 1.0 M HCl‚ 0.1 M HCl‚ 0.1 M KSCN‚ 0.002 M KSCN (in 0.1 M HCl)‚ 0.2 M FeCl3 (in 0.1 M HCl)‚ and 0.002 M FeCl3(in 0.1 M HCl). Using the prepared stock solutions‚ the standard (Table 1) and Unknown (Table 2) solutions were prepared. Table 2. Preparation of Standard Solutions 0.10 M KSCN 0.002 M FeCl3 0.1 M HCl Blank 2.0 ml 0.0 ml 8 ml S1 2.0 ml 0.1 ml 7
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Determination of the Solubility Product Constant of Calcium Hydroxide Introduction The equilibrium constant for the solubility equilibrium between an ionic solid and its ions is called solubility constant [1] ‚ Ksp of the solute. For example‚ the solubility product is defined by MxAy(s) ⇋xM(aq)y++ yA(aq)x- (1) Where M is the metal cation‚ A is the anion‚ x and y are the corresponding charges of the ions. The equilibrium expression is Ksp=[MY+]x[AX-]Y (2)
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! ! ! ! Determination of Gas Constant R through Mg and HCl Reaction ! ! ! ! ! !1 of !9 IB Chemistry SL (Jr) Candidate: Yunha Kim Objective ! Candidates will react Magnesium with Hydrochloric acid and collect Hydrogen. The grams of the produced Hydrogen will be calculated and compared to the theoretical yield of Hydrogen. ! Controlled Variables ! Mass of Magnesium Ribbon This will be kept constant as the objective is to determine the Gas Constant (R). If this
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Experiment 5- Standardization of NaOH and determination of Molarity of an unknown Acid Objectives 1. Preparation and standardization of a 0.1M NaOH solution 2. To learn the technique of titration 3. Determination of the concentration of an unknown diprotic acid. Introduction Titration can be traced to the origins of volumetric analysis‚ which began in the late eighteenth century. Study of analytical chemistry began in France and the first burette was made by Francois Antoine Henri
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objective of the experiment was to prepare Benzilic acid by multistep synthesis starting with benzaldehyde. In this setup however‚ product of the first step‚ Benzoin‚ is provided thereby omitting the first step involving the conversion of benzaldehyde. For this experiment‚ the microscale techniques of reflux‚ crystallization‚ and melting-point determination were used. Utilizing these techniques a product yield of 93% for benzil and 57% for Benzilic acid was obtained‚ as well as a melting point range of
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the NMR J values angle is at 167 which both prove the erythro-2‚3-dibromo-3-phenylpropanoic. Determination of the Stereochemistry of 2‚3-dibromo-3-phenylpropanoic acid. Introduction The purpose of this experiment was to determine the mechanism of the reaction of trans-cinnamic acid with the addition of bromines to 2‚3-dibromo-3-phenylpropanoic acid. An addition of bromine was added to trans-cinnamic acid and it is necessary to determine whether the intermediates were syn or anti addition or a mixture
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This solution served as the source of ionic Iron for the remainder of the lab and was labeled “stock ionic Iron solution.” Next‚ a 50-mL aqueous ionic Iron and FerroZine® complex solution was prepared by adding 5.00mL stock ionic Iron‚ 3-mL of acetic acid buffer‚ 2-mL of 5% hydroxylamine hydrochloride‚ allowing five minutes for hydroxylamine to reduce Fe3+ to Fe2+‚ adding 2.5-mL of 0.01 M FerroZine® solution‚ and mixing well. A single beam Agilent technologies CARY60-UV-Vis Spectrophotometer was then
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Spectrophotometric Determination of the Equilibrium Constant of a Reaction DEPARTMENT OF MATERIALS‚ METALLURGICAL AND MINING ENGINEERING‚ COLLEGE OF ENGINEERING July 26‚ 2012 ------------------------------------------------- ABSTRACT ------------------------------------------------- Before proceeding to test the next solution‚ we must first clean the cuvette‚ using similar steps earlier. First‚ we rinse with water‚ then with the solution‚ and then we fill it up and test
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Hydrocinnamic acid underwent bromination using N-bromosuccinimide and AIBN. As one lab partner set up the reflux apparatus‚ the other measured the chemicals used in the lab experiment. 2.10 g of hydrocinnamic acid was used. It was observed as white and had a slight cinnamon smell. The amount of NBS was 2.49g and was measured in the fume hood. AIBN was measured at .030 g. 10 mL of acetic acid was also obtained. The reflux apparatus consisted of a 25 mL flask with a stir bar in a water bath. The chemicals
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De-esterification for Synthesis of Benzoic Acid BATCH REACTOR Shane Bulk Chris Crosley David McGuire Max Skula Yunjing Song Shriram Sundarraj Nelson Zhou 155:416 Process Laboratory II Professor Jerry Sheinbeim January 28 – February 28‚ 2014 ABSTRACT The observed reaction that took place in this experiment was the de-esterification of ethyl benzoate to form benzoic acid. This experiment was used to determine the rate constant k of the synthesis of benzoic acid at different temperatures
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