presence of an aromatic ring‚ alkene group and carbonyl group. CNMR showed the presence of an aromatic ring‚ carbonyl group and a methyl group. HNMR showed the presence of an aromatic ring‚ alkene group and carbonyl. Using the rule of 13 and the adjustment for oxygen‚ the predicted structure of the anise oil was C10H12O with 5 degrees of unsaturation. Since the aromatic ring is 4 degrees of unsaturation by itself‚ the last degree of unsaturation was most likely an alkene
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C H A P T E R 5 Basic Concepts from Organic Chemistry 5.1 | INTRODUCTION The fundamental information that environmental engineers and scientists need concerning organic chemistry differs considerably from that which the organic chemist requires. This difference is due to the fact that chemists are concerned principally with the synthesis of compounds‚ whereas environmental engineers and scientists are concerned‚ in the main‚ with how the organic compounds in liquid‚ solid‚ and gaseous wastes
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The percent yield of the isopentyl acetate was 74.3% and this low percent yield could have occurred due to some amount of gas escaping from reflux apparatus’ top or apparatus was not fully closed so that some of the heat escaped and did not proceed the reaction well‚ leaving reagents. Another source of error could be that some of the organic layer could have been transferred along with the aqueous layer when the aqueous layer was getting separated from the organic layer by a pipette. One of the
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Introduction The objective of this experiment was to carry out an elimination reaction on 2-methylalcohol with an acid to produce alkenes as a product. The product formed is separated through distillation. Because more than one alkene product can result from the reaction‚ Gas Chromatography is used to analyze the composition of the product mixture. IR spectrometry is also carried out to confirm the product. Procedure This experiment was carried out as described in Class Pak. The heat source
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Chapter 18 Ethers & Epoxides; Thiols and Sulfides Assigned Reading from McMurry: Read Sections 18.1 through 18.9; not responsible for “Focus on … Epoxy Resins & Adhesives‚ pp. 697-698). Recommended Problems from McMurry: 18.1a-e;18.18.2;18.3a-d; 18.4; 18.5a-d; 18.6a-b; 18.7a-b; 18.8; 18.9; 18.10; 18.11; 18.12a‚b; 18.13a‚b; 18.14a-c; 18.16a-f; 18.17; 18.18; 18.19a-c; 18.20; 18.21; 18.22; 18.23a-e; 18.24a-I; 18.25a-f; 18.26a-d; 18.27; 18.28; 18.29ad; 18.30a-e; 18.31; 18.32; 18.33; 18.34; 18
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"antiperiplanar"). This fact is important to remember since the stereochemistry of the resulting alkene (Z or E; cis or trans) is often controlled by the hydrogen which is removed in the elimination reaction. In the reaction shown below‚ the hydrogen on the carbon bearing the methyl group cannot become anti-to the halogen‚ hence the elimination occurs on the secondary carbon‚ to give the unfavored less substituted alkene. The rate-limiting transition state in the E1 reaction is again‚ carbocation formation
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Name: Date: Score: /72 INTRODUCTION TO ISOMERISM AND ALKENES EXERCISES 1. Draw the one constitutional isomer that is missing from column 1 of Model 1. (2 points) 2. Draw ten skeletal representations constitutional isomers missing from column 2 in Model 1 as you can. (Hint: Other than cyclohexane‚ there are 11 ways to draw a six-carbon backbone that contains a ring. Plus there are isomers of cyclohexane that do not contain a ring.) (10 points) 3. Are
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the naming convention of the alkanes except that the suffix -yne is used instead of -ane. For alkynes above propyne the position of the double bond must be specified in the name. Alkynes are unsaturated hydrocarbons and are generally very reactive. Typical reactions involve the addition of hydrogens or halogens. Alkynes are hydrocarbons that contain a carbon–carbon triple bond. Because of its triple bond‚ an alkyne has four fewer hydrogens than the corresponding alkane. Therefore‚ the
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Alloy - An alloy is a substance made by melting two or more elements together‚ at least one of them a metal. An Example: Examples of alloys include brass‚ bronze‚ 14k gold‚ and sterling silver. covalent bond - A covalent bond is a chemical link between two atoms in which electrons are shared between them. An Example: There is covalent between the oxygen and each hydrogen in (H 2 O). Each of the bonds contains two electrons - one from a hydrogen atom and one from the oxygen atom. Both atoms
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Chemistry IGCSE Paper 6 revision guide You can change the temperature and concentration used (not both at the same time though) You need to keep the diameter of the conical flask the same‚ if it is thinner then the cross will disappear sooner‚ the cross also has to be the same‚ volumes too (This set up is mostly if you want to test the gases‚ otherwise you can use the standard set up) The limestone cycle: 1. Burn the limestone
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