had gone to completion. 3. IR Spectroscopy Peaks Peak Functional Group1 2362.05 cm-1 Very weak band 1712.90 cm-1 (Strongest peak) C=O (ketone) 1598.22 cm-1 C=C (aromatic) 1450.50 cm-1 C=C (aromatic) 1150.63 cm-1 Very weak band 735.43 cm-1 =C–H (alkene) 669.78 cm-1 Very weak band Attached is a published spectrum from: http://sdbs.db.aist.go.jp/sdbs/cgi-bin/direct_frame_top.cgi Discussion 1. According to the melting point measured‚ the final product was quite pure. The melting point range determined
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Diels-Alder reactions are steriospecific (cis-alkenes form cis substituted and trans-alkenes form trans-substituted); this is called syn addition‚ the configuration of dienophiles is always retained in the product. The diene and dienophile react in such a way that the endo product is formed rather than the exo
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NPTEL – Chemistry – Reagents and Organic reactions Module II Lecture 14 Reduction Reactions 2.1.1 Lithium Aluminum Hydride (LAH) 2.1.1.1 Introduction Lithium aluminum hydride (LAH) is a strong reducing agent with chemical formula LiAlH4. It can reduce a variety of functional groups such as aldehydes‚ esters‚ acids‚ ketones‚ nitriles‚ epoxides and azides. It vigorously reacts with water and all the reactions are performed in polar aprotic solvents. 2.1.1.2 Preparation It was first
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The percent yield of meso-1‚2-dibromo-1‚2-diphenylethane was calculated to be 66.36% and with a melting point of 235.1°C. Therefore‚ it can be concluded that this experiment was successfully conducted as the percent yield obtained is only 33.64% off from the equilibrium point‚ and because the melting point met the literature value. The percent yield for the product was less than 100%‚ indicating that were experimental errors‚ such as an undesirable side reaction‚ or more likely‚ an incomplete reaction
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also be cracked by thermal or steam cracking. ================================ Properties of Alkanes and Alkenes Alkenes have similar physical properties to the corresponding alkanes. They are both non-polar molecules with weak dispersion forces being the only intermolecular forces involved. Ethene‚ propene‚ and butenes are gases at room temp. as are the corresp alkanes. The higher alkenes‚ like the alkanes‚ are liquids. However‚ they are different chemically. ================================
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SYLLABUS FOR ENTRANCE TEST 2012 UNIVERSITY OF HEALTH SCIENCES LAHORE‚ PAKISTAN STRUCTURE OF ENTRANCE TEST PAPER 2012 Sr.# Subject No. of Questions 1. PHYSICS 44 2. CHEMISTRY 58 3. ENGLISH 30 4. BIOLOGY 88 TOTAL 220 CONTENTS PHYSICS Syllabus TOS Self Test Questions CHEMISTRY Syllabus TOS Self Test Questions ENGLISH Syllabus Self Test Questions BIOLOGY Syllabus TOS Self Test Questions PAGE# 1-5 6 7-9 10-21 22 23-28 29-34 35-36 37-44 45 46-51 PHYSICS
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Isolation of Eugenol from Cloves by Steam Distillation and its Identification by Infrared Spectroscopy Eim A. Chemist CHEM 303 June 16‚ 2005 INTRODUCTION “Essential oils” are the volatile components associated with the aromas of many plants.1 In this experiment‚ the essential oil eugenol (the main component of oil of cloves) will be isolated from ground cloves using the technique of steam distillation‚ which is often used to isolate liquid natural products from plants.2 The principle
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positive result for the chloride test. Bromine Br2 (l or aq) A dark red liquid - orange-brown fumes‚ yellow-orange aqueous solution. The other common orange-brown gas is nitrogen dioxide (i) Shake with a liquid alkene. (ii) Mix with silver nitrate solution. (ii) Decolourised. See alkene test. (ii) Cream ppt. of silver bromide as in the test for bromide. (i) Forms a colourless organic dibromo-compound >C=C< + Br2 ==> >CBr-CBr< (ii) Ag+(aq) + Br-(aq) ==> AgBr(s) Any soluble bromide gives
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Subject Content Most of the objectives specified in this section relate to Knowledge with Understanding‚ although some indication has been given as to where the skills of Handling Information and Solving Problems may be developed. Teachers are reminded that‚ in the written papers‚ 40% of the marks are allocated to these higher ’thinking’ skills. In almost every section‚ students should therefore be given practice at dealing with unfamiliar situations so that these higher thinking skills can be developed
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Topic Acid-Base Theory (Unit 1) Acid-Base Theory (Unit 2) Isomerism (Unit 1) Isomerism (Unit 2) Nomenclature Reaction Mechanism (Unit 1) - Introduction to Mechanism Reaction Mechanism (Unit 2) - Nucleophilic substitution Reaction Mechanism (Unit 3) - Nucleophilic substitution Reaction Mechanism (Unit 4) - Nucleophilic substitution Reaction Mechanism (Unit 5) - Nucleophilic substitution Reaction Mechanism (Unit 6) - Nucleophilic substitution Reaction Mechanism (Unit 7) - Elimination Reaction Mechanism
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