Chemical Analysis’ Review: Pure water has a pH = 7 Autodissociation: H2O (( H3O+ + OH- K = [H3O+][OH-]/[H2O] -log[H3O+] = 7 [H3O+] = 10-7 M = [OH-] [H2O] = 55.56 M K = 1.8 x 10-16 ; pKa = 15.74 pKa is the acid dissociation constant; low pKa (strong acid‚ high pKa (weak acid we can also write Kw = [H3O+][OH-] Kw = 10-14 In water‚ pH + pOH = 14 pH scale Strong Acids: Complete dissociation of the acid in water: HA (
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Experiment 1: "A cis to trans conversion" Saturday‚ June 25‚ 2005 4:19 PM Notes on Theory • Alkenes o They are hydrocarbons with a C=C double bond • Double bonds are stronger and more reactive than single bonds o Hydrocarbons with double bonds used to be known as "olefins"‚ because they had an oily appearance • "Oleum" means oil • "Ficare" means make • Isomers o Geometric isomers have the same molecular formula‚ but a different geometric arrangement • They also have different physical properties
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Application of linear algebraic equation for chemical engineering problem The chemical engineering system models often outcome of set of linear algebraic equations. These problems may range in complexity from a set of two simultaneous linear algebraic equations to a set involving 1000 or even 10‚000 equations. The solution of a set two or three linear algebraic equations can be obtained easily by the algebraic elimination of variables or by the application of cramer’s rule. However for systems involving
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Experiment #6: Colorimetric Determination of pH Almira‚ Faerie Carleen Lucile L. Gallardo‚ Charlotte O. Group #6‚ Chemistry 18.1‚ MHEG1‚ Ma’am Arlou Angeles September 23‚ 2013 I. Abstract The acidity of the four unknown solutions were determined with the use of colorimetry using McIlvaine’s buffer solutions varying in proportion of its constituents (disodium phosphate and citric acid). These buffer solutions were subjected to the addition of corresponding pH indicators and the variation of
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ACID/BASE You might need to know the following K values: CH3COOH Ka = 1.8 x 10–5 Benzoic Acid Ka = 6.5 x 10–5 HNO2 Ka = 4.5 x 10–4 NH3 Kb = 1.8 x 10–5 HF Ka = 7.2 x 10–4 H2S Ka = 5.7 x 10–8 HSO4– Ka = 1.2 x 10–2 HS– Ka = 1.2 x 10–13 HCOOH Ka = 1.8 x 10–4 HOCl Ka = 3.0 x 10–8 SIMPLE ACIDS AND BASES 1. According to the Brønsted–Lowry definition‚ which species can function both as an acid and as a base? (A) Cl– (B) SO42– (C) NH4+ (D) HCO3– (E) H3O+ 2. Which of the following
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Stephen G. Abelada BS ChE IV Date Submitted: January 4‚ 2012 ChE 171 Assignment 1. Essential and Non-essential Amino acids Amino acids are organic compounds which contain both an amino group and a carboxyl group and may be divided into two groups basing on whether they are produced internally by the human body or not: essential and non-essential amino acids (hyperphysics.phy-astr.gsu.edu‚ 2012). An essential amino acid (indispensable amino acid) is an amino
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Research Question: To investigate how varying the pH of bromothymol blue affects the absorbance value of the solution which determines the equilibrium constant (pKa) of the indicator. Variables: Variables Variables Measured Method of measurement Independent pH of the six buffer solution A pH probe attached to a data-logger will be used to measure pH Dependent Absorption of the buffer solutions at wavelength 435.0nm and 617.0 nm A spectrophotometer (±0.001) will be used to measure absorbance
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minutes. The dark black solution was filtered through a gravity filtration system‚ leaving dark residue behind on the filter paper‚ and colorless to slightly pink liquid in the beaker. Then‚ 9 mL of sodium acetate buffer‚ to maintain a relatively constant pH and 1.8 mL of acetic anhydride were added to the solution‚ and then it was mixed and heated for about 5 minutes. Then‚ to induce crystallization‚ the beaker was placed in an ice bath. The slightly white‚ powdery crystals were collected using the
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Chemistry102 5/7/2013 Lecture Presentation Chapter 17 Additional Aspects of Aqueous Equilibria John D. Bookstaver St. Charles Community College Cottleville‚ MO © 2012 Pearson Education‚ Inc. Common Ion Effect HA(aq) + H2O(l) ⇔ A−(aq) + H3O+(aq) • Adding a salt containing the anion NaA‚ which • is the conjugate base of the acid (the common ion)‚ shifts the position of equilibrium to the left This causes the pH to be higher than the pH of the acid solution 9lowering the H3O+ ion concentration
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Irresistible? By Mikayla Messing 8/3/12 Section 623 Abstract To examine the effectiveness of buffers by titrating two sets of five different solutions using HCl and NaOH and monitoring the pH change of the various solutions. The data collected shows that the buffer systems made with sodium acetate and acetic acid were effect when titrated with the strong acid and the strong base. Comparison of all the solutions shows that the concepts of buffers holds true for the results from the experimentation
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