Review Packet for midterm 1 10/2/2013 Nikki Stefanko & Stephanie Ventura 24 1. Cortisol is a steroid hormone produced by the adrenal cortex that is released in response to stress and a low level of blood glucocorticoids. OH O OH HO H H
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Compounds: Benzoic Acid – NaOH: Ion – (induced) dipole and van der Waals forces Benzoic Acid – NaHCO3: Ion – (induced) dipole and van der Waals forces Phenol – NaOH: Hydrogen Bonding‚ Ion – dipole‚ and van der Waals forces For Basic Compound(s): Aniline – HCl: Ion – dipole and van der Waals forces For Neutral Compounds: Benzyl alcohol – H2SO4: Hydrogen bonding and van der Waals forces Benzaldehyde – H2SO4: Ion – (induced) dipole and van der Waals forces Q2. Write the balanced chemical
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indigo and azo dyes and use them to observe their effectiveness in dying natural fabrics. The results of the experiment are summarized below. Weights Starting materials: • Aniline-3-sulfonic acid: 0.493 g • Salicylic Acid: 0.398 g Azo Dye: 0.515 g % Yield: (actual/theoretical) x 100 • Actual 0.515 g • Theoretical: o Aniline-3-sulfonic acid: (0.493 g/173.19g/mol) = 0.00285 mol o Salicylic acid: (0.398 g/152.15 g/mol) = 0.00262 mol o Limiting Reagent: Salicylic acid o Product: 0.00262 mol x (322
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Additional Questions: 1. H H H C C H H C C H C H H C H H Compound A Compound A is an intermediate compound found in a production plant attempting to synthesise n-hexane. a) List three physical properties of alkynes. b) Give the IUPAC name of compound A. [3 marks] [2 marks] c) There are several ways to form the final product from Compound A. An operator has decided to use Pt catalyst to react with Compound A. Write the complete chemical reaction equation. [3 marks] d) The quality assurance
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atoms and label each chiral carbon as (R) or (S). 7. Give the stereochemical relationships (same compound‚ structural isomers‚ distereomers‚ or enantiomers) between each pair of isomers. 8. Consider the following free radical bromination of an enantiomerically pure alkane. Is the product formed as a single enantiomer or a racemic mixture? Is the product optically active or optically inactive? Explain your answers. Substitution and elimination reactions (Chpt 11): 9.
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EXPERIMENT 8 BOILING POINT n-Butyl Alcohol n-Butyl Alcohol‚ a four carbon straight chain alcohol‚ is a volatile‚ clear liquid with a strong alcoholic odor; miscible with water. It is flammable strongly with a luminous flame. Formula: C4H9OH Boiling point: 118 ºC Melting point: -89 ºC Tert-Butyl Alcohol Tert-Butyl Alcohol or “2-methyl-2-propanol” is the simplest tertiary alcohol. It is one of the four isomers of butanol. Tert-Butanol is a clear liquid (or a colorless solid‚ depending on
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Classification Tests for Carboxylic Acid and Derivatives Mary Catherine Sarte‚ John Emmanuel Sy‚ Allurie Umel‚Franklin Yap‚ Mary Christine YouIntroduction Carboxylic acids derivatives are simply groupsof compounds that contain a carbonyl group butwith an electronegative atom attached to thecarbon. The difference in the structure leads to amajor change in reactivity. The reactions of thesegroups of compounds involve nucleophilicsubstitution. Although there are abundant kindsof carboxylic acid derivatives
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Chemistry 140A TOTAL POSSIBLE: 250 Fall‚ 2009 POINTS MISSED: - 0 Second Midterm Exam-250 points 11/19/09 TOTAL: 250 DO NOT OPEN THIS EXAM UNTIL INSTRUCTED TO DO SO.....FILL OUT THE FOLLOWING INFORMATION NOW: . LAST NAME (Print): KEY FIRST NAME (Print): Ima PID: __________________________________________________ SIGNATURE: __________________________________________
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using the resulting aldehyde‚ along with 2‚4-dimethylpyrole‚ a BODIPY dye was obtained [36]. To facilitate intersystem crossing‚ the 2- and 6- positions of the boradiazaindacene ring system were iodinated with an iodic acid-iodine mixture [37]. Bromination at the same positions was performed via N-bromosuccinamide (NBS) [38]. 8-Palmitoyl-1‚ 3‚ 5‚ 7-tetramethyl-2‚ 6 diiodo-4-bora‚ 3a‚ 4a-diaza-s-indacene was obtained by the iodination of 8-palmitoyl-1‚ 3‚ 5‚
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HNO2 Chemical Structure: pH: 6.70 Classification: Weak acid Uses: Nitrous acid is useful for destroying sodium azide solutions‚ which are toxic and potentially explosive. It can also be used to prepare diazonium salts‚ which combine with anilines and phenols to form brightly colored azo compounds.
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