School of Chemistry @ Pietermaritzburg University of KwaZulu Natal Chemistry 310 Substitution reaction of Molybdenum Hexacarbonyl: the use of infrared spectroscopy as a structural tool in metal carbonyl chemistry. Abstract The synthesis of isomer A and B of [Mo(CO)4(PPh3)2] were prepared from molybdenum hexacarbonyl‚ sodium borohydride and triphenylphosphine with a % yield of 79% and 8.5% respectively. Two isomer was identified using IR spectra and from isomer A four C≡O stretching
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sometimes known as the carbonyl process is a technique created by Ludwig Mond in 1890 to extract and purify nickel. The process was used commercially before the end of the 19th century. It is done by converting nickel oxides (nickel combined with oxygen) into pure nickel. Spheres of Nickel made by Mond’s Process. This process makes use of the fact that carbon monoxide complexes with nickel readily and reversibly to give nickel carbonyl. No other element forms a carbonyl compound under the
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KINDS OF TEST TO CLASSIFY HYROXY- AND CARBONYL-CONTAINING COMPOUNDS Jane Catherine SP. Villanueva‚ Edenn Claudine C. Villaraza‚ Lorenz Oliver C. Villegas and Cristel Bernice T. Wee Group 10 2G-Medical Technology Organic Chemistry Laboratory ABSTRACT Hydroxyl group refers to a functional group containing OH- when it is a substituent in an organic compound. It is also known as the characteristic functional group of alcohols and phenols. On the other hand‚ carbonyl group refers to a divalent chemical
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Grignard reagent The carbon bonded to the metal is an excellent nucleophile and base. This carbon with carbanion character can partake in typical nucleophilic reactions such as nucleophilic substitution or carbonyl addition. The experiment performed is an example of carbonyl addition using a Grignard reagent. On critical aspect of the a reaction involving a Grignard reagent is that it must be performed under dry conditions. The carbanion is a very strong base and can abstract protons
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secondary amine. This secondary amine bridges the ketone to the Beta-lactam ring that is a four membered ring with nitrogen bonded to a carbonyl group. That ring is attached to another ring that is considered a cyclopentyl-thioether that is a cyclic ether with a sulfur atom instead of an oxygen atom. The last functional group is the Carboxylic acid‚ which is a carbonyl group bonded to an alcohol group. The beta-lactam ring and the cyclic thioether are‚ collectively‚ also considered a bicyclic compound
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We performed two procedures in which we reduced methyl acetoacetate. For the first procedure we produced a racemic mixture of Methyl (S)-3-Hydroxyacetate and Methyl (R)-3-Hydroxyacetate. For the second we produced only one of the enantiomer products depending on which enantiomer of Tartaric Acid was used. A reduction is a reaction which generally means adding more carbon-hydrogen bonds to a compound. In a reduction reaction the oxidation number of a carbon atom decreases. The opposite is an oxidation
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anhydride. This difference in electronegativities causes one of the carbonyl groups in acetic anhydride to break its carbon-oxygen double bond with the oxygen atom taking the pair of electrons from the pi bond and results in a negative charge on oxygen and a positive charge on carbon. The positive charge on carbon is then stabilized by the donation of a lone pair of electrons from oxygen‚ which is attached to both of the carbonyl groups in acetic anhydride‚ and results in the formation of an O=C bond
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manual used for this experiment two characteristic carbonyl IR stretches of MesMo(CO)3 occur strongly around 2000 cm-1. The stretches at 1940 and 1855 cm-1 in the IR ATR spectra are possible indicators of carbonyl stretches in the compound that was made. The solution cell IR spectra had two stretches at 1981 and 1876 cm-1 are also indicative of carbonyl stretches in the compound that was made. The IR ATR spectra that was collected has a similar carbonyl stretch pattern similar in the (benzene)chromium
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Synthesis and Structure of Alcohols Alcohols can be considered organic analogues of water. H O H R O H Alcohols are usually classified as primary‚ secondary and tertiary. H R H OH H primary R R OH R R OH OH R secondary tertiary phenol Alcohols with the hydroxyl bound directly to an aromatic (benzene) ring are called phenols. Nomenclature of Alcohols (Normally any compound’s name which ends in –ol is an alcohol of some sort) IUPAC rules that:
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www.ccsenet.org/ijc International Journal of Chemistry Vol. 2‚ No. 2; August 2010 One-pot Preparation of β–amino Carbonyl Compounds by Mannich Reaction Using MgO/ZrO2 as Effective and Reusable Catalyst Deepak.M. Nagrik (Corresponding author) Department of Chemistry‚ PLIT and MS Buldana-443001‚ M.S.‚ India E-mail: dmnagrik@rediffmail.com D.M.Ambhore P.G.Department of Chemistry‚ Jijamata Mahavidyalaya Buldana-443001‚ M.S.‚ India Manoj.B. Gawande (Corresponding author) Departamento de Química
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