Since mammals do not synthesize their own folic acid‚ PABA inhibitors such as sulfanilamide selectively kill bacteria without injuring the host (Figure 1). One of the most well-known preparation techniques of sulfanilamide is achieved by treating aniline with excess chlorosulfonic acid via replacement of hydrogen with a sulfonyl chloride group. This reagent forms sulfonic acid first before being converted into a sulfonyl chloride by the excess chlorosulfonic acid (Scheme
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www.ccsenet.org/ijc International Journal of Chemistry Vol. 2‚ No. 2; August 2010 One-pot Preparation of β–amino Carbonyl Compounds by Mannich Reaction Using MgO/ZrO2 as Effective and Reusable Catalyst Deepak.M. Nagrik (Corresponding author) Department of Chemistry‚ PLIT and MS Buldana-443001‚ M.S.‚ India E-mail: dmnagrik@rediffmail.com D.M.Ambhore P.G.Department of Chemistry‚ Jijamata Mahavidyalaya Buldana-443001‚ M.S.‚ India Manoj.B. Gawande (Corresponding author) Departamento de Química
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plus the poisonous chemicals necessarily handled in the production of dye stuffs. Prior to 1917 the making of aniline products in this country for use as dye stuffs amounted to next to nothing. Our company had‚ however‚ been making aniline products since 1907‚ and in no inconsiderable quantities‚ for use as explosives; so that while the dye industry is fairly new to us‚ the nature of aniline and a number of its allied products is fairly familiar. The first hazard we meet in the dye industry is from
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appearance. It is also known as N phenylacetamide‚ acetanil or acetanilide. Its former trade name was antifebrin. As mentioned earlier acetanilide can be produced by reacting acetic anhydride with aniline. C6H5NH2 + (CH3CO)2O → C6H5NHCOCH3 + CH3COOH (http://www.mendelset.com/articles/680/preparation-recrystallization-acetanilide) (regensburg.de/Fakultaeten/nat_Fak_IV/Organische_Chemie/Didaktik/Keusch/Grafik/box_brom_ar1.gif) The second figure illustrates the process used in the laboratory
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by : Directorate of Education‚ Delhi SOME IMPORTANT REASONING BASED QUESTIONS OF ORGANIC CHEMISTRY 1. Chlorobenzene is less reactive than chloromethane. Ans. In chlorobenzene‚ each carbon atom of benzenering is sp2 hyridised and is electron withdrawing. Chlorine atom donates a lone pair of electron and acquire positive charge. The negative charge is delocalised on ortho and para position by resonance. C-Cl bond acquires partial double bond character and is 169 pm as compared to 17.0 pm in chloromethane
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indigo and azo dyes and use them to observe their effectiveness in dying natural fabrics. The results of the experiment are summarized below. Weights Starting materials: • Aniline-3-sulfonic acid: 0.493 g • Salicylic Acid: 0.398 g Azo Dye: 0.515 g % Yield: (actual/theoretical) x 100 • Actual 0.515 g • Theoretical: o Aniline-3-sulfonic acid: (0.493 g/173.19g/mol) = 0.00285 mol o Salicylic acid: (0.398 g/152.15 g/mol) = 0.00262 mol o Limiting Reagent: Salicylic acid o Product: 0.00262 mol x (322
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Superstitions About Rats | Question 1Characterisation of Aniline | Zoe la Grange | 17036283 | | Tutor: Peet van Aardt Group 51 The Characterisation of Aniline “Oh‚ for heaven’s sake‚ Aniline‚ look at you standing there… Say something girl‚ do something‚ start living in the real world!... Just get to class!”. By looking at this extract from the short story Superstitions About Rats by Lesley Emanuel‚ one can already tell that the character‚ Aniline‚ does not go out of her way to stand up for herself
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Organic Chemistry II Laboratory (ABCT357) Although studying fundamental theories of chemistry in the class is important to understand the concept of chemistry‚ carrying out experiments to corroborate the theories is also important. It is very important for students to get used to experiments in order to speed up their experiments. Expt.1. Acetylation of α-D-glucopyranose Add slowly 2.5 g (0.014 mol) of powdered D-glucose in small portions (roughly in 7-10 portions and 5 min for each addition)
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acetanilide was produced by acetylation of aniline with acetic anhydride. The crude acetanilide was dissolved in a solvent in a heated water bath. The solution was cooled slowly in an ice bath as crystals form out. As the compound crystallizes from the solution‚ the limiting reagent Aniline and the percent yield of 96% was obtained. Introduction: This experiment involves four functional groups common in organic chemistry. The substrate (reactants) which are Aniline and Acetic anhydride are both liquids
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have on an aromatic benzene ring. The substituents being tested are aniline‚ anisole‚ acetamide (acetanilide)‚ and phenol. All four of these groups are either para or ortho activating. Bromination is the reaction that will be carried out. The melting point ranges of the final products will be taken in order to determine their identities and reactivity. It is predicted that substitution order from most to least reactive should be aniline‚ phenol‚ anisole‚ and acetamide. Theory: Regioselectivity and
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