2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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How sodium chloride concentration affects the germination‚ growth and development of Brassica rapa. Osumi‚ K.‚ Nihei‚ B.‚ Takanishi‚ K.‚ Nakamura‚ C.‚ Warehime‚ R. Period 2. 03/05/17 Introduction: To have a successful germination‚ the plant seed needs a sufficient amount of water and oxygen present. Other conditions include room temperature‚ and the amount of light intake. Hydration of a seed‚ is an essential step for seed germination (Martínez-Andújar‚ 2014). Plants tend to germinate better in
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Testing the effect of concentration on rate of reaction Plan: We are investigating the effect of nitric acid on calcium carbonate. We are doing this experiment‚ as we would like to understand the effect that acid rain has on limestone. We also want to understand how acid can have an effect on rate of reaction. The word equation for the reaction that will take place is: Calcium Carbonate + Nitric Acid Calcium Nitrate + Carbon Dioxide + Water The balanced symbol equation
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Effect of changes in substrate concentration on the reaction rate of an enzyme IB biology Internal Assessment 3/23/12 Research Question: Effect of changes in substrate concentration amount on the reaction rate of an enzyme Introduction: In this experiment‚ the substrate is hydrogen peroxide. The purpose of this investigation is to find out the relationship between the substrate concentration and the rate of reaction. Substrates are molecules that are acted upon by enzymes. For instance
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Weight of ampicillin sodium (mg) What weight (in mg) of ampicillin sodium (C16H18N3NaO4S) will provide 144 mg of ampicillin base (C16H19N3O4S)? 27. Weight of potassium permanganate (g) Potassium permanganate is normally made as a concentrated solution which is then diluted prior to
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Chemical Reaction Lab Well #1 CuCl2 + Al (shot) - Bubbling - Turning reddish-maroon - 33oC Well #2 CuCl2 + Al (foil) - Bubbling‚ but less than well #1 - Turning black - 28oC Well #3 CuCl2 + Zn - Turned black then red - No bubbling - 29oC Well #4 CuCl2 + NH4OH - Cloudy - No bubbling - 26oC Well #5 CuCl2 + NaCO3 - Not mixing with CuCl2 - Heterogeneous - 25oC Well #6 CuCl2 + AgNO3 - Cloudy - Top layer is white -29oC 1. The more pronounced reaction was the aluminum
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6 did not. Not many fruits and vegetables contain preservatives simply because they come from nature. One of the items contained Sodium Benzoate‚ a small percentage of people are extremely sensitive to sodium benzoate and can experience asthmatic attacks and other allergic reactions when they take in the preservative. A more normal problem is the combination of sodium benzoate and citric acid and ascorbic acid. When these ingredients mix‚ they form benzene‚ a cancer-causing chemical linked with leukemia
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Molecular Formula Molecular Weight Boiling Point Melting Point Density Amylene CH3CH=C(CH3)2 70.13 g/mol 36 oC -134 oC 0.662 g/ml Hydrobromic Acid HBr 80.91 g/mol 126 oC -11 oC 1.490 g/ml 2-Bromo-2-MethylButane C5H11Br 151.05 g/mol 107 oC 1.18 g/ml Sodium bicarbonate NaHCO3 84.007 g/mol Decomposes at melting point unknown 2.159 g/ml Diethyl ether C2H5OC2H5 74.12 g/mol 34.6 °C −116.3 °C 0.7134 g/ml In this lab we use electrophilic addition of a hydrogen halide to an alkene to make 2-bromo-2-methylbutane
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and the sodium hydroxide. When using glassware in experiments‚ it must be flushed out to make sure that cross contamination does not happen and that the only thing that would then be coating the beaker is the distilled water. When all of the glassware has been cleaned‚ some sodium hydroxide should be placed in a plastic weighing boat next to the scales and place the second weighing boat on the scales and weigh it then click the on tare button to set it back to zero and weigh out 1g of sodium hydroxide
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produced from the reaction between p-anisaldehyde and acetophenone with the presence sodium hydroxide. The reaction also showed the importance of an enolate and the role it played in the mechanism. Sodium hydroxide acts as a catalyst in this experiment and is chosen because of its basic conditions and pH. The acetophenone carries an alpha hydrogen that has a pKa between 18 and 20. This alpha hydrogen is acidic because of its location near the carbonyl on acetophenone. When the sodium hydroxide is added
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