SCH4U Thermochemistry Test Review Try all the problems previously assigned‚ look at the problems in your textbook‚ and try these: 1. Be sure to understand the following vocabulary: Thermochemistry Thermochemical Equation System Surrounding Calorimetry calorimeter Heat temperature thermal energy chemical energy Open‚ closed‚ isolated/insulated systems enthalpy change Molar enthalpy Exothermic changes Endothermic changes Hess’s Law Heat capacity specific heat capacity combustion
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Purpose: The purpose of the experiment is to calculate the enthalpy change occurring in the first of reaction of sodium hydroxide with hydrochloric acid and sodium hydroxide with ammonium chloride. Using Hess’ Law and the results for the enthalpy change of the first two reactions should give the enthalpy change of the third reaction of ammonia with hydrochloric acid. Procedure: Part 1: Construct a calorimeter of two nested stereophony cups where the cover has a hole to fir a thermometer. Measure
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15.2 Born-Haber Cycle Our calculations of enthalpies so far have involved covalent substances. Now we need to look at the enthalpy changes involved in the formation of giant ionic lattices. Lattice enthalpy is defined as either the: ’the enthalpy change that occurs when one mole of a solid ionic crystal is broken into its ions in the gaseous state‚ at standard temperature and pressure. Because all the bonds in the ionic lattice are broken‚ it is an endothermic process‚ ∆H is positive. ’ The
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Thermochemistry IB questions 1. Ammonium nitrate‚ NH4NO3‚ dissolves readily in water according to the equation: NH4NO3(s) NH4+(aq) + NO3-(aq) H = 28kJ mol-1 Which of the following contribute(s) to the occurrence of this process? I. The system moves to lower enthalpy. II. The system becomes more disordered. a. I only b. II only c. Both I and II d. Neither I nor II 2. Which substance has the largest lattice energy? a. NaF b. KCl c. MgO d. CaS 3. A certain reaction is spontaneous
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Thermochemistry Laboratory Report Abstract The purposes of these three experiments are to determine the heat capacity of a calorimeter and with that data‚ confirm Hess’s Law and observe enthalpy changes within reactions. By measuring the change in temperature that occurs with the interaction of two different reactants‚ we were able to determine both the calorimeter constant and the change in enthalpy of a given reaction. The results were rather mixed‚ as some numbers more closely resembled the
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experiment‚ we us naphthalene as a fuel in bomb calorimeter which naphthalene powder is turned to pellet using pellet press. The fuel is burnt at constant volume condition in a high pressure container (the bomb). The whole bomb‚ pressurized with excess of oxygen. The mass of iron wire‚ ma =0.02g. The mass of naphthalene pellet with iron wire‚ mb =0.38g. The bomb is submerged in 850g of water and the initial temperature of calorimeter state temperature of calorimeter water before burning the fuel‚ Ti is
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CHEMISTRY – THERMOCHEMISTRY INTRODUCTION WORKSHEET DEFINE THE FOLLOWING TERMS: BOILING BOILING POINT CALORIE (OR KILOCALORIE) CONDENSATION DEPOSITION ENDOTHERMIC REACTION ENTHALPY OF FUSION ENTHALPY OF VAPORIZATION EVAPORATION EXOTHERMIC REACTION FREEZING HEAT JOULE MELTING MELTING POINT SPECIFIC HEAT SUBLIMATION TEMPERATURE VAPOR VAPOR PRESSURE VAPORIZATION VOLATILE Name ________________________________________ Date ______________ Period _______ HONORS CHEMISTRY – THERMOCHEMISTRY INTRODUCTION
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molar enthalpy change of a neutralization reaction Principle H2SO4(aq)+2NaOH(aq)=Na2SO4(aq)+2H2O(l) The reaction is a exothermic reaction‚ when the heat released by it is absorbed by water‚ the temperature of the water increases. The heat produced by the reaction can be calculated if it is assumed that all the heat is absorbed by the water. Heat change of reaction=-heat change of water =-mH2O×cH2O×△TH2O As the water has gained the heat produced by the reaction‚ the heat change of reaction is negative
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* . Introduction Endothermic reactions are accompanied by the absorption of heat. The dissolving of ammonium nitrate in water is an example of an endothermic reaction. The solution resulting from this mixture is colder than either the ammonium nitrate or the water. This is the simple explanation of what happens in an instant ice pack. The more detailed information will be discussed in the following paragraphs. Cold Packs Most cold packs come with a fabric cover made to absorb condensation and
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LAB OF ENTHALPY CHANGE IN COMBUSTION Objective: Determine the Enthalpy change of combustion ΔHc of three different alcohols. Methanol‚ Ethanol and Isopropilic acid. Procedure: 1. Fill the spirit micro burner with Ethanol and weight it 2. Pour 100 cm3 of water into the aluminum cup 3. Arrange the cup a short distance over the micro burner 4. Measure the temperature of water 5. When the temperature of the water has risen by 10°C‚ record the temperature. 6. Reweight
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