organic compounds that consist of only C and H atoms. They include the alkanes‚ alkenes‚ alkynes‚ and aromatic hydrocarbons. Because of their relatively non-polarity‚ all hydrocarbons are insoluble in water. When hydrocarbons burn in sufficient oxygen‚ carbon dioxide and water are the sole products. The main structural difference among hydrocarbon families is the presence of double or triple bonds between carbon atoms. The alkanes are saturated organic compounds‚ or those with only single bonds. Unsaturated
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6-Dimethyl-3-heptyne 1‚6-Heptadiyne Common names: prefix the substituents on the triple bond to the name “acetylene” IUPAC name: Common name: 2-Butyne D imethylacetylene 1-Buten-3-yne Vinylacetylene Physical Properties Similar to alkanes and alkenes of comparable molecular weight and carbon skeleton 2-Butyne 1-Pentyne Melting Point Formula (°C) -81 HC CH CH3 C CH -102 CH 3 CH2 C CH -126 -32 CH3 C CCH3 CH 3 ( CH2 ) 2 C CH -90 1-Hexyne CH 3 ( CH2 ) 3 C CH 1-Octyne
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Lewis base. Orbital hybridization: sp3‚ sp2‚ sp. Conjugated double bonds and resonance 2. Classification of organic compounds Nomenclature: homologues series‚ alkanes‚ cycloalkanes‚ alkene‚ alkynes‚ alkyl halides‚ alcohols‚ amines‚ aldehydes‚ ketones and carboxylic 4 acids and their derivatives. 3. Stereochemistry Conformations of alkanes and cycloalkanes. Isomerism and optical activity. Structural isomers and stereoisomers. Geometrical isomers: (E) and (Z) systems. Enantiomers and diastereoisomers;
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precipitate‚ etc) 2) work in a short amount of time (instantly to 5 minutes) 3) only work with one functional group The following are chemical tests that we will use in this class. Some cover two related functional groups (such as the bromine test for alkenes and alkynes)‚ while other only a specific subcategory of that functional group (such as the iodoform test for methyl ketones). In some cases there can be false positives (compounds which do not have the functional group still give a result test)
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Infrared Spectroscopy Organic Chemistry Lab 301A B. The purpose of this lab is to study Infrared Spectroscopy‚ which focuses on the study of the electromagnetic spectrum. The area to be studied is the infrared region‚ which is made up of gamma‚ X‚ and UV rays. We want to be able to identify spectra’s to their complementary structures. The background of this experiment particularly deals with the study of compound structure determination‚ and traits. We must be aware of the functional groups
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phenol soln in test tube + 1 drop FeCl3 soln Aliphatic and Aromatic Hydrocarbons/ Alkenes Bromination in Light (Free Radical Bromination) (Reacts with alkanes) Reagent: Br2 in H2O Observation: decolorization‚ brown ( colorless Procedure: 2 drops of test compound in test tube+ 1 drop 0.05 M Br2 in H2O‚ shake well‚ record observations Bromination in Dark (Electrophilic Addition Halogenation) (Reacts with alkenes) Reagent: Br2 in H2O Observation: decolorization‚ brown ( colorless Procedure:
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which more than one pair of electrons are shared between two carbon atoms. Based on the nature of the carbon chain they are grouped as‚ * Chain form * Branched form * Ring form Alkane‚ Alkene and Alkyne…….. Alkane: Saturated hydrocarbons. Represented by a general form >> CnH2n+2 Alkenes: Unsaturated hydrocarbons. Double bond between two carbon atoms. Represented
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uncontrollable environmental factors. Introduction An alkyl halide or haloalkane is composed of hydrocarbons with a halogen attached to a sp3-hybridized carbon. It resembles an alkane with a halogen attached to it. Halogens are fluorine‚ chlorine‚ bromine‚ and iodine. Any of these halogens seen to be attached to an alkane‚ could then be identified as alkyl halides. They are generally polar because of the electronegativity difference of carbon (2.5) with the halogen (2.5-4.0). However‚ most alkyl
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found that the product yielded 1‚2-epoxydihydronaphthalene as well as naphthalene. Introduction In 1990‚ professor E.N. Jacobsen reported that chiral manganese complexes had the ability to catalyze the asymmetric epoxidation of unfunctionalized alkenes‚ providing enantiomeric excesses that regularly reaching 90% and sometimes exceeding 98% . The chiral manganese complex Jacobsen utilized was [(R‚R)-N‚N’-Bis(3‚5-di-tert-butylsalicylidene)-1‚2- cyclohexanediaminato-(2-)]-manganese (III) chloride
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Classification Tests for Hydrocarbons Authors: Goldie Ann Tejada‚ Allain Joseph S. Templo‚ Kristinlyn Trajano‚ Kevin Viray‚ Quennie Yu Group 10‚ 2F-PH‚ Faculty of Pharmacy‚ University of Santo Tomas ABSTRACT The test compounds undergo different physical and chemical tests to differentiate their intrinsic physical properties and chemical properties. Physical state‚ color‚ and odor were noted through simple observation. Miscibility of the test compounds were noted through color change or a warming
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