ONE-SCHOOL.NET Short Notes: Form 5 Chemistry Rate or Reaction Calculation Rate of Reaction (Average Rate) Rates of reaction = Quantity change of reactants/products Total time for the reaction If the quantity change is immeasurable Rates of reaction = 1 Total time for the reaction Find the Rate From a Graph Average Rate Rates At an Instant The rate of reaction is equal to the slope of the graph The rate of reaction at an instant‚ t‚ is equal to the of quantity against
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Comparison of the rate of reaction and yield of glycerol in saponification with different triglycerides Chemistry EE Candidate number: 0019 Word count: 3974 TABLE OF CONTENTS CONTENTS 2 INTRODUCTION 2 RESEARCH QUESTION 5 BACKGROUND INFORMATION 5 METHODOLOGY 10 DATA PRESENTATION AND PROCESSING 13 CONCLUSION 24 EVALUATION 24 BIBLIOGRAPHY 26 Introduction In 1779‚ Carl W. Scheele‚ a Swedish chemist‚ discovered a new transparent‚ syrupy liquid by heating olive oil and litharge . This
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2.5. Characterization Methods 1H–NMR and 13C–NMR spectra of HPPP‚ BOMP and HVPA were taken in CDCl3 on Bruker DPX–300 MHz spectrometer using tetramethylsilane (TMS) as an internal standard. FT–IR spectra of the synthesized compounds‚ HPPP‚ BOMP‚ HVPA and photocrosslinked polymers were recorded on Perkin-Elmer system 2000 (4000–400 cm–1) spectrometer‚ using KBr pellets. Medium pressure mercury vapour lamp to the power output of 125W/cm2 was used for the photocrosslinking study. The viscosity of the
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ChemActivity 10: Exercises 1. Draw a complete mechanism including the intermediate and most likely product for the reaction of each alkene below with H-X. H + H Cl + Cl Cl + + Br H Br H I Br + H I H + I H 2. Draw a complete mechanism of each pair of reactant including any favorable rearrangements and all important resonance structures of all intermediates. Reactant Pair 1 Cl H Br 1 + Cl No shift stable benzylic carbocation H: shift H H Br
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breaking. Nucleophiles‚ electrophiles and free radicals. Lewis acid and Lewis base. Orbital hybridization: sp3‚ sp2‚ sp. Conjugated double bonds and resonance 2. Classification of organic compounds Nomenclature: homologues series‚ alkanes‚ cycloalkanes‚ alkene‚ alkynes‚ alkyl halides‚ alcohols‚ amines‚ aldehydes‚ ketones and carboxylic 4 acids and their derivatives. 3. Stereochemistry Conformations of alkanes and cycloalkanes. Isomerism and optical activity. Structural isomers and stereoisomers. Geometrical
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soluble if heated. Also tested was the reactivity of cyclohexane and cyclohexene in sulfuric acid which tested to prove reactivity between cyclohexene but not cyclohexane. Finally tested was the reaction between bromine and alkenes‚ which showed reaction between the more polar alkenes than non polar. Introduction
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single bonds) or unsaturated (wherein there are one or more carbon-to-carbon multiple bonds). Saturated aliphatic hydrocarbons are alkanes while unsaturated aliphatic hydrocarbons are alkenes and alkynes. The general formula of alkanes‚ alkenes and alkynes are CnH2n+2‚ CnH2n‚ and CnH2n-2‚ respectively. Alkanes‚ alkenes and alkynes can be open-chain (acyclic)‚ cyclic‚ unbranched or branched. Aromatic hydrocarbons are represented by a
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4th form Chemistry questionnaire 1. All of the following structures show the same molecule‚ except one. Which structure is different? H H H H A) H -- C -- C -- C --- C -- H B) CH3 CH2 CH2 CH3 H H H H H H -- C -- H CH3 C) H H D)
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ETHERS Classification of Ethers: Symmetrical ethers – two groups attached to O are identical Ex. CH3CH2OCH2CH3 – diethyl ether Unsymmetrical ethers – two groups attached to O are not identical Ex. CH3CH2OCH3 – ethyl methyl ether Physical Properties of Ethers: Ethers have much lower boiling points compared to alcohols of comparable MWs. BPs of ethers increases with increasing MW. BPs of isomeric ethers increase with increasing alkyl chain length. BPs of ethers are about the
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Hydrolysis of an alkyl nitrile on boiling with mineral acid or alkalis yield corresponding carboxylic acid . R–CN +H2O RCOOH +NH3 CH3–CN + 2H2O+HCL CH3COOH + NH4CL 4. BY OXIDATIVE CLEAVAGE OF ALKENES: Alkenes when heated with alkaline KMNO4 are cleaved at double bond to form carboxylic acids. R–CH=CH–R +4[O] 2RCOOH H3C–CH=CH–CH3 + [O] 2CH3COOH REACTIONS OF
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