3-perylenepentanol‚ M4 39‚ 51 To a solution of 3-perylenepent-4-ynol‚ M3 (0.32 g‚ 0.957 mmol) in THF (20 mL)‚ Pd/C (600 mg‚ 3 wt% on activated carbon) was added. Nitrogen gas was turned off‚ hydrogen gas balloons were used to supply H2 gas to the flask. The reaction mixture was stirred for 15 h under hydrogen atmosphere at room temperature. Ethyl acetate was added to the reaction mixture and the Pd/C was removed by filtration. Solvent was removed in vacuo to afford 3-perylenepentanol as yellow solid
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In 1974 scientists warned that certain industrial chemicals‚ e.g.‚ chlorofluorocarbons (CFCs) and to a lesser extent‚ halons and carbon tetrachloride‚ could migrate to the stratosphere. There‚ sunlight could free the chlorine or bromine atoms to form chlorine monoxide or other chemicals‚ which would deplete upper-atmospheric ozone. A seasonal decrease‚ or "hole‚" discovered in 1985 in the ozone layer above Antarctica was the first confirmation of a thinning of the
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Old Dominion University ORGANIC 214 Alkene Addition Submitted by: Alkene addition: Bromination of (E) Stilbene Introduction: In this lab we used the greener approach‚ which involves the addition of bromine across a double bond. When bromine reacts with E-stilbene (trans-1‚2-diphenylethene)‚ two new chiral carbons are created from the sp2 carbons‚ therefore 3 different dibrominated stereoisomers are possible: meso-(1R‚2S)‚ or the raceminc mixture-(1R‚2R) or (1S‚2S)-dibromo-1‚2-diphenylethane
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Maleic anhydride underwent the Dials-Alder reaction with distilled cyclopentadiene as the dienophile. The reaction was a cycloaddition which produced cis-Norbornene-5‚6-endo-dicarboxylic Anhydride surface. (1) Product one had a mass of 9.351 grams and product two had a mass of 9.572 grams. The theoretical yield was found to be 10.047 grams‚ which makes the percent yield to be 93.07%. Melting Points were found to confirm the purity of the product. Product one had a melting point of 163.7-164
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Supplemental Questions 1. A newer form of the periodic table has been established‚ but is not universally used at this time. Go to http://www.sciencenews.org/view/generic/id/67938/description/Periodic_table_gets_some_flex and read the article to answer the following questions: a. What has been added to the new table? The atomic weights of oxygen‚ hydrogen‚ lithium‚ boron‚ carbon‚ nitrogen‚ silicon‚ sulfur‚ chlorine and thallium are now be expressed as intervals. b. Why is this addition important
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Basic Stoichiometry PhET Lab Let’s make some sandviches! Introduction: When we bake/cook something‚ we use a specific amount of each ingredient. Imagine if you made a batch of cookies and used way too many eggs‚ or not enough sugar. YUCK! In chemistry‚ reactions proceed with very specific recipes. The study of these recipes is stoichiometry. When the reactants are present in the correct amounts‚ the reaction will produce products. What happens if there are more or less of some of the reactants
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Chemistry Unit 1 – Revision Questions Chemistry 1A 1) Define an element. How many are there in the Periodic Table? 2) Write a table with the charges and masses of protons‚ neutrons and electrons. 3) Define atomic number and mass number. 4) Draw electron (energy level) diagrams for Be‚ S‚ Al‚ Cl and K. Also‚ write down the number of protons and neutrons for each. Finally‚ write the symbols (with mass no. and atomic no.) 5) Why have all Group 7 elements (halogens) got similar chemical properties
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MONTREAL PROTOCOL: The Montreal Protocol on Substances That Deplete the Ozone Layer (a protocol to the Vienna Convention for the Protection of the Ozone Layer) is an international treaty designed to protect theozone layer by phasing out the production of numerous substances believed to be responsible forozone depletion. The treaty was opened for signature on September 16‚ 1987‚ and entered into force on January 1‚ 1989‚ followed by a first meeting in Helsinki‚ May 1989. Since then‚ it has undergone
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on a piece of copper metal? What will happen if a drop of solution containing copper ions is placed on a piece of silver metal? Chlorine and bromine are both non-metals (both negative in compounds) and both are used for disinfecting and bleaching. What will happen if chlorine is added to a solution containing bromide ions? What will happen if bromine is added to a solution containing chloride ions? Permanganate ions (MnO4-) react with iron(II) ions (Fe2+) in acid solution. What about the ratio
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Phenol‚ also a strong electron donating group had a melting point similar to the literature value for 2‚4‚6-tribromophenol. This was expected since phenol is strongly activating and would add bromine to all ortho‚ para positions. Acetanilide is not as strongly activating‚ and is sterically hindered with a bulky group. Thus the melting point is the same as the literature value for 4-dibromoacetanilide which adds to the para position. Similarly
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