important natural examples are citric acid (in lemons) and tartaric acid (in tamarinds). Salts and esters of carboxylic acids are called carboxylates. When a carboxyl group is deprotonated‚ its conjugate base forms a carboxylate anion. Carboxylate ions are resonance stabilized and this increased stability makes carboxylic acids more acidic than alcohols. Carboxylic acids can be seen as reduced or alkylated forms of the Lewis acid carbon dioxide; under some circumstances they can be decarboxylated to
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prepare acetanilide which could then be readily brominated to form a mono-brominated product‚ with the bromine positioned at either the ortho‚ meta or para position on the aromatic ring. Acetic anhydride is very reactive towards nucleophiles and this reactivity is the result of the difference in electronegativities of the carbon and oxygen atoms that are bonded in acetic anhydride. This difference in electronegativities causes one of the carbonyl groups in acetic anhydride to break its carbon-oxygen double
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are chemical reactions in which the oxidation state (or oxidation number) of atoms has changed. Oxidation can be observed through the loss of electrons or an increase in oxidation state by an atom‚ ion or molecule. Reduction describes the gain of electrons or decrease in oxidation state of an atom‚ ion or molecule. However‚ there are many processes that are classed as redox even though no electron transfer occurs‚ for example those reactions that involves covalent bonds. Reduction reactions can be
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Duma’s method. The types of compounds that were used in testing were all functional groups‚ Aldehyde‚ Ketone‚ Alcohol and‚ Ester. Functional groups are a portion of a molecule that give the molecules its properties‚ they are the centers of chemical reactivity. The structures of the functional groups used in testing are displayed in Figure 1.0. Figure 1.0 Structure of Functional Groups to Distinguish from Within the
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UTAR FHSC1134 Inorganic Chemistry Trimester 3 Experiment 1 ________________________________________________________________________ Title: Investigating the Properties of Period 3 Oxides Aim: To examine the oxides of Period 3 elements and describe their structure and bonding. Introduction: Generally‚ there are oxides of metals and non-metals. Metals burn in oxygen to form basic oxides while non-metals form acidic oxides. Structurally‚ they are covalent or ionic compounds. You are to
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Physical properties of Group II metals Ionization The process of removing an electron from an isolated atom (or an ion) to form a cation. First ionization: M(g) M+(g) + 1e- Second ionization: M+ (g) M2+(g) + 1e- Ease of ionization All the Group II elements have two electrons in their outer shell. They can lose these electrons to form positive ions. e.g. Ca Ca2+ + 2e- In the neutral atoms the electrons are held to the nucleus by the electrostatic attraction
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triphenylmethanol. Introduction: The Grignard reagents are alkyl magnesium halides‚ R-Mg-X were first introduced in 1900. These reagents are usually prepared by reacting one atom with one molecule or by other means magnesium and alkyl halide in the presence of dry alcohol free ether.
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for the following systematic names. Systematic name: meta-Bromopropoxybenzene Systematic name: 1-Isopropoxycyclopentene 18.2 Synthesis of Ethers The Williamson Ether Synthesis R + O an alkoxide C X R SN2 an alkyl halide methyl & 1o best; X = Cl‚ Br‚ I‚ OTos O C ether product Example: O Na + Sodium phenoxide CH3 Br O CH3 Phenyl methyl ether (anisole) + Na Br + X SP
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Metals and Non-metals Elements are divided mainly into two groups on the basis of physical and chemical properties – Metal and Non-metal. Metals: Part - I Physical Properties of Metals:- Hardness:- Most of the metals are hard‚ except alkali metals‚ such as sodium‚ potassium‚ lithium‚ etc. Sodium‚ potassium‚ lithium etc. are very soft metals‚ these can be cut using knife. Strength:- Most of the metals are strong and have high tensile strength. Because of this big structures are made using metals
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HEMIN TEST Introduction Ludwig Karl Teichmann was a Polish anatomist and physician who made an enduring contribution to forensic science with his discovery of the Hemin test or Teichmann test for hemoglobin. Also called the Teichmann crystal‚ this is a test that is used on dried stains to determine whether or not blood is present. Dr. Teichmann made his forensic discovery in 1853. His microcrystalline test remains in use today as a means of identifying whether or not dried stains at a crime
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