004:121 Organic I Fall 2010 Final Exam Please read each question carefully before answering. Answer the questions in ink in the spaces provided inside. If you make changes as you go‚ please make sure your final answer is clearly indicated. Scratch papers are available at the end. Total points = 150. You have 120 min. Good Luck! ____________________________________________________________ ___________ Grading: Q.# 1. 2. 3. 4. 5. 6. 7. Score (Max) __________ (60 pts) __________ (18
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Hydrogen Peroxide & Inorganic Peroxy Compounds Hydrogen Peroxide Hydrogen peroxide (H2O2) is the simplest peroxide (a compound with an oxygen-oxygen single bond). It is also a strong oxidizer. Hydrogen peroxide is a clear liquid‚ slightly more viscous than water. In dilute solution‚ it appears colorless. Reactions Decomposition Hydrogen peroxide decomposes exothermically into water and oxygen gas spontaneously: 2 H2O2 → 2 H2O + O2 This process is thermodynamically favorable. It has
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Reactions of pyridine Introduction: 1. Pyridine structure: 2. Iupac name: Pyridine‚ other name: Azine & Azabenzene. *Important commercial alkyl pyridinium compound is α - methyl- pyridine (2)‚ βpicoline (3)‚ γ- picoline ( 4 ) ‚ 2‚6 - lutidine ( 5 ) ‚ 3‚5 - dimethyl- pyridine ( 6 ) ethyl-2 - methyl- pyridine ( 7 ) and 2‚4‚6 - collidine ( 8 ) . In general‚ the alkyl -substituted pyridine as many other precursors used in pyridine E-commerce. From these further alkyl substituted pyridine
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hydrogens on the α-carbons because of their weakly acidic characteristics. Therefore‚ the product yields of acylation‚ alkylation‚ and an aldol condensation are low and unwanted side reactions occur (Figure 1). In order to avoid side reactions‚ a good nucleophile needs to be produced
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Chapters 2.8-2.10: alcohols‚ halogenoalkanes‚ mechanisms and spectra Consolidation questions 1. Give the names of the two primary alcohols with the molecular formula C4H10O. butan-1-ol 2-methyl propan-1-ol 2. Write the equation‚ using state symbols‚ for the reaction of ethanol with sodium. CH3CH2OH(l) + Na(s) CH3CH2O-Na+(alc) + ½ H2(g) 3. Name the organic product above. Sodium ethoxide 4. Give the names and structural formulae for the two possible products
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Unit 2 Biosynthesis and Degradation of Nucleotides Module Description: This module is designed to learn the biosynthesis of nucleotides 1 Topics (Chapter 22.4/25.1: Lehninger Principles of Biochemistry) 1. De Novo Purine Nucleotide Synthesis Begins with PRPP 2. Purine Nucleotide Biosynthesis Is Regulated by Feedback Inhibition 3. Pyrimidine Nucleotides Are Made from Aspartate‚ PRPP‚ and Carbamoyl Phosphate 4. Pyrimidine Nucleotide Biosynthesis Is Regulated by Feedback Inhibition 5. Nucleoside
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Chapter 1 MULTIPLE CHOICE QUESTIONS Topic: Atomic Orbitals 1. A) B) C) D) E) In quantum mechanics a node (nodal surface or plane) is: a place where Ψ is negative. a place where Ψ is positive. a place where Ψ = 0. a place where Ψ2 is large. a place where Ψ2 is negative. Ans: C Topic: Atomic Orbitals‚ Molecular Orbitals 2. When the 1s orbitals of two hydrogen atoms combine to form a hydrogen molecule‚ how many molecular orbitals are formed? A) 1 B) 2 C) 3 D) 4 E) 5 Ans:
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Structural Effects on Stability and Reactivity. Organic Chemstry Laboratory Structural Effects on Stability and Reactivity Introduction The concepts of stability and reactivity are fundamental to understanding chemistry. In this chapter we consider first the thermodynamic definition of chemical stability. We then consider chemical kinetics (Section 3.2) and how it can provide information about reactivity. We also explore how structure influences stability and reactivity. We want to learn how
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Skin Sensitization: Reaction Mechanistic Applicability Domains for Computational Structure Activity Relationship A POJECT REPORT AS PART OF THE REQUIRMENT OF THE DEGREE OF MASTER OF SCIENCE SUBMITED BY: BALDANIYA BHAVESHKUMAR B. Enrollment no: CUG/2011/0193 SCHOOL OF ChEMICAL SCIENCEs Central University of Gujarat GAndhinagar – 382030 India May 2013 Dedicated to my Parents And Friends STATMENMT I hereby declare that the work exemplified in this dissertation is the result
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Preparation and Characterization of Hydrocarbons Miranda‚ Marilyn1‚ Comaling‚ Leif Anthony B.2 1Professor‚ School of Chemical Engineering‚ Chemistry and Biotechnology‚ Mapua Institute of Technology; 2Student (s)‚ Subject/Section‚ School of Chemical Engineering‚ Chemistry and Biotechnology‚ Mapua Institute of Technology ABSTRACT Hydrocarbons are compounds that only contain carbon and oxygen atoms. Alkanes‚ alkenes‚ alkynes and aromatic rings are the four classifications of hydrocarbons
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